A coordination polymer of (Ph_3P)AuCl prepared by post-synthetic modification and its application in 1-hexene-hexane separation

Ana J. Nunez; Lindsey N. Shear; Naween Dahal; Ilich A. Ibarra; JiWoong Yoon; Young Kyu Hwang; Jong-San Chang; Simon M. Humphrey

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A coordination polymer of (Ph_3P)AuCl prepared by post-synthetic modification and its application in 1-hexene-hexane separation

机译：后合成改性制备的（Ph_3P）AuCl配位聚合物及其在1-己烯/正己烷分离中的应用

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PCM-10 is a porous phosphine coordination material based on Ca(Ⅱ) and tris(p-carboxylated) triphenylphosphine. The material provides a unique 3-dimensional surface of P(Ⅲ) Lewis base sites, which is ideal for post-synthetic functionalization. The addition of Au(Ⅰ) yields an advanced material that can selectively adsorb 1-hexene over n-hexane at room temperature.

机译：PCM-10是一种基于Ca（Ⅱ）和三（对羧基）三苯膦的多孔膦配位材料。该材料提供了独特的P（Ⅲ）Lewis基位的三维表面，非常适合合成后功能化。 Au（Ⅰ）的加入产生了一种先进的材料，该材料可以在室温下通过正己烷选择性吸附1-己烯。

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《Chemical Communications》 |2011年第43期|p.11855-11857|共3页
作者
Ana J. Nunez; Lindsey N. Shear; Naween Dahal; Ilich A. Ibarra; JiWoong Yoon; Young Kyu Hwang; Jong-San Chang; Simon M. Humphrey;
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Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712-0165, USA;

Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712-0165, USA;

Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712-0165, USA;

Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712-0165, USA;

Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology, PO Box 107, Yusung, Daejeon 305-600, Korea;

Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology, PO Box 107, Yusung, Daejeon 305-600, Korea;

Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology, PO Box 107, Yusung, Daejeon 305-600, Korea;

Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712-0165, USA;

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A coordination polymer of (Ph_3P)AuCl prepared by post-synthetic modification and its application in 1-hexene-hexane separation

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