Homochiral 3D metal-organic frameworks from chiral ID rods: 6-way helical packing

摘要

The chiral 3D MOFs resulted from the packing of chiral ID SBBs were studied. It was demonstrated that the final packing pattern is sensitively dependent on the dimension of SBBs. In addition, we were able to identify a new plywood-like network from ligand 2H_2 exhibiting an unprecedented six-way chiral helical packing motif, which extends the list of invariant rod packings.