A linear single-molecule magnet based on [Ru~Ⅲ(CN)_6]~3-

Kasper S. Pedersen; Jan Dreiser; Joscha Nehrkorn; Maren Gysler; Magnus Schau-Magnussen; Alexander Schnegg; Karsten Holldack; Robert Bittl; Stergios Piligkos; Hφgni Weihe; Philip Tregenna-Piggott; Oliver Waldmann; Jesper Bendix

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A linear single-molecule magnet based on [Ru~Ⅲ(CN)_6]~3-

机译：基于[Ru〜Ⅲ（CN）_6]〜3-的线性单分子磁体

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We report the synthesis, structure and magnetic properties of the first molecular cluster and single-molecule magnet to incorporate [Ru~Ⅲ(CN)_6l~3-. Frequency-domain Fourier-transform THz-EPR (FDFT THz-EPR) and magnetic susceptibility measurements indicate strongly anisotropic Mn-Ru exchange interactions.

机译：我们报道了第一个分子簇和单分子磁体的合成，结构和磁性，并结合了[Ru〜Ⅲ（CN）_6l〜3-。频域傅里叶变换THz-EPR（FDFT THz-EPR）和磁化率测量表明强烈各向异性的Mn-Ru交换相互作用。

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来源
《Chemical Communications》 |2011年第24期|p.6918-6920|共3页
作者
Kasper S. Pedersen; Jan Dreiser; Joscha Nehrkorn; Maren Gysler; Magnus Schau-Magnussen; Alexander Schnegg; Karsten Holldack; Robert Bittl; Stergios Piligkos; Hφgni Weihe; Philip Tregenna-Piggott; Oliver Waldmann; Jesper Bendix;
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Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100, Copenhagen, Denmark;

Swiss Light Source, Paul Scherrer Institut, CH-5232 Villigen PSI Switzerland;

Physikalisches Institut, Universitdt Freiburg, D-79104 Freiburg, Germany;

Physikalisches Institut, Universitdt Freiburg, D-79104 Freiburg, Germany;

Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100, Copenhagen, Denmark;

Institut fur Silizium-Photovoltaik, Helmholtz-Zentrum Berlin, D-12489 Berlin, Germany;

Institut fur Methoden und Instrumente der Forschung mit Synchrotronstrahlung, Helmholtz-Zentrum Berlin, D-12489 Berlin, Germany;

Institut fur Physik, Freie Universitdt Berlin, D-10115 Berlin, Germany;

Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100, Copenhagen, Denmark;

Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100, Copenhagen, Denmark;

Laboratory for Neutron Scattering, Paul Scherrer Institut, 5232 Villigen PSI Switzerland;

Physikalisches Institut, Universitdt Freiburg, D-79104 Freiburg, Germany;

Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100, Copenhagen, Denmark;

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A linear single-molecule magnet based on [Ru~Ⅲ(CN)_6]~3-

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