A G-octamer scaffold via self-assembly of a guanosine-based Au(Ⅰ)isonitrile complex for Au(Ⅰ)-Au(Ⅰ) interaction

Xiangtai Meng; Toshiyuki Moriuchi; Masatoshi Kawahata; Kentaro Yamaguchi; Toshikazu Hirao

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A G-octamer scaffold via self-assembly of a guanosine-based Au(Ⅰ)isonitrile complex for Au(Ⅰ)-Au(Ⅰ) interaction

机译：基于鸟苷的Au（Ⅰ）异腈配合物自组装的G-八聚体支架，用于Au（Ⅰ）-Au（Ⅰ）相互作用

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A guanosine-based Au(Ⅰ) isonitrile complex was demonstrated to serve as the reliable scaffold via self-assembly, wherein the quartet and octamer were formed in the absence and presence of a potassium ion, respectively, exhibiting a switchable emission based on Au(Ⅰ)-Au(Ⅰ) interaction.

机译：鸟嘌呤基Au（Ⅰ）异腈配合物通过自组装被证明是可靠的支架，其中四元组和八聚物分别在不存在和存在钾离子的情况下形成，并显示出基于Au（a）的可转换发射。 Ⅰ）-Au（Ⅰ）相互作用。

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《Chemical Communications》 |2011年第16期|p.4682-4684|共3页
作者
Xiangtai Meng; Toshiyuki Moriuchi; Masatoshi Kawahata; Kentaro Yamaguchi; Toshikazu Hirao;
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Department of Applied Chemistry, Graduate School of Engineering,Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan;

Department of Applied Chemistry, Graduate School of Engineering,Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan;

Pharmaceutical Sciences at Kagawa Campus Tokushima BunriUniversity, 1314-1 Shido, Sanuki, Kagawa 769-2193, Japan;

Pharmaceutical Sciences at Kagawa Campus Tokushima BunriUniversity, 1314-1 Shido, Sanuki, Kagawa 769-2193, Japan;

Department of Applied Chemistry, Graduate School of Engineering,Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan;

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A G-octamer scaffold via self-assembly of a guanosine-based Au(Ⅰ)isonitrile complex for Au(Ⅰ)-Au(Ⅰ) interaction

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