Carbenoid-mediated N-O bond insertion and its application in the synthesis of pyridines

Xinxin Qi; Lu Dai; Cheol-Min Park

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Carbenoid-mediated N-O bond insertion and its application in the synthesis of pyridines

机译：类胡萝卜素介导的N-O键插入及其在吡啶合成中的应用

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Highly efficient synthesis of 3-hydroxypyridines has been developed based on carbenoid-mediated N-O bond insertion. Treatment of δ-diazo oxime ethers with dirhodium complex Rh_2(tfacam)_4 rapidly provides a variety of pyridines in 5-10 minutes in good to excellent yields.

机译：基于类胡萝卜素介导的N-O键插入，已经开发了3-羟基吡啶的高效合成。用二价铑配合物Rh_2（tfacam）_4处理δ-重氮肟醚，可在5-10分钟内快速提供各种吡啶，并具有良好的收率。

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《Chemical Communications》 |2012年第91期|p.11244-11246|共3页
作者
Xinxin Qi; Lu Dai; Cheol-Min Park;
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Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore;

Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore;

Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore;

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机译：4-硝基吡啶-N-氧化物和吡啶-3-羧酸N-氧化物的燃烧焓-吡啶-N-氧化物衍生物中N-O键的解离焓
2. 1,4-Dihydropyridyt complexes of magnesium: synthesis by pyridine insertion into the magnesium-silicon bond of triphenylsilyls and catalytic pyridine hydrofunctionalization [J] . Lemmerz L. E., Spaniol T. P., Okuda J. Dalton transactions: An international journal of inorganic chemistry . 2018,第36期

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3. Stereoselective Synthesis and Applications of Compounds with N-O Bonds [J] . Faisca Phillips Ana Maria Current Organic Synthesis . 2016,第5期

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4. High Accuracy Placement, and In-Situ Reflow or Thermo-Compression Bonding Enabling High Density and Fine Pitch in 3D-IC with Chip to Wafer Bonding Approach, Illustrated by an Application using Micro-Insertion [C] . Gilbert Lecarpentier, Jean Stephane Mottet, Francois Marion International Conference and Exhibition on Device Packaging . 2009

机译：高精度放置，以及原位回流或热压缩键合，在3D-IC中实现高密度和细间距，通过使用微插入的应用说明的应用
5. Synthesis and anti-HIV-1 activities of novel N-O bond incorporataed nucleosides. [D] . Pan, Shifeng. 2000

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6. Computational Study of Selected Amine and Lactam N-Oxides Including Comparisons of N-O Bond Dissociation Enthalpies with Those of Pyridine N-Oxides [O] . Arthur Greenberg, Alexa R. Green, Joel F. Liebman 2020

机译：所选胺和内酰胺N-氧化物的计算研究包括与吡啶N-氧化物的N-O键离解焓的比较
7. Computational Study of Selected Amine and Lactam N-Oxides Including Comparisons of N-O Bond Dissociation Enthalpies with Those of Pyridine N-Oxides [O] . Arthur Greenberg, Alexa R. Green, Joel F. Liebman 2020

机译：所选胺和内酰胺N-氧化物的计算研究，包括与吡啶N-氧化物的N-O键离解焓的比较
8. Insertions of Nitriles and Pyridine into the ZR-SI Bond of (n5-C sub 5 H sub5)(n5-C sub 5 Me sub 5) Zr(Si(SiMe sub 3)3)Me [R] . Woo, H. G., Tilley, T. D. 1990

机译：将腈和吡啶插入（n5-C sub 5 H sub5）（n5-C sub 5 me sub 5）Zr（si（sime sub 3）3）me的ZR-sI键中

Carbenoid-mediated N-O bond insertion and its application in the synthesis of pyridines

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