Induction of chirality in porphyrin-(bis)calixarene assemblies: a mixed covalent-non-covalent vs a fully non-covalent approach

Alessandro DUrso; Pietro Francesco Nicotra; Giovanni Centonze; Maria Elena Fragala; Giuseppe Gattuso; Anna Notti; Andrea Pappalardo; Sebastiano Pappalardo; Melchiorre F. Parisi; Roberto Purrello

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Induction of chirality in porphyrin-(bis)calixarene assemblies: a mixed covalent-non-covalent vs a fully non-covalent approach

机译：卟啉-（双）杯芳烃组装物中的手性诱导：混合共价-非共价与完全非共价方法

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摘要

CD and UV-vis measurements were carried out to demonstrate chirality induction-promoted by chiral covalently linked groups and non-covalently bound ⊿- and Λ-[Ru(phen)_3]~(2+) enantiomers-in metallo-porphyrin-calixarene and metallo-porphyrin-bis-calixarene non-covalent assemblies, respectively.

机译：进行了CD和UV-vis测量，以证明由手性共价连接基团和非共价键合的⊿-和-[Ru（phen）_3]〜（2+）对映异构体-在金属卟啉-杯芳烃中诱导的手性和金属卟啉-双杯芳烃非共价组装体。

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《Chemical Communications》 |2012年第34期|p.4046-4048|共3页
作者
Alessandro DUrso; Pietro Francesco Nicotra; Giovanni Centonze; Maria Elena Fragala; Giuseppe Gattuso; Anna Notti; Andrea Pappalardo; Sebastiano Pappalardo; Melchiorre F. Parisi; Roberto Purrello;
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Dipartimento di Scienze Chimiche, Universitd di Catania, Viale A. Doria 6, 95125 Catania, Italy;

Dipartimento di Scienze Chimiche, Universitd di Catania, Viale A. Doria 6, 95125 Catania, Italy;

Dipartimento di Scienze Chimiche, Universitd di Catania, Viale A. Doria 6, 95125 Catania, Italy;

Dipartimento di Scienze Chimiche, Universitd di Catania, Viale A. Doria 6, 95125 Catania, Italy;

Dipartimento di Chimica Organica e Biologica, Universita di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina, Italy;

Dipartimento di Chimica Organica e Biologica, Universita di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina, Italy;

Dipartimento di Scienze Chimiche, Universitd di Catania, Viale A. Doria 6, 95125 Catania, Italy;

Dipartimento di Scienze Chimiche, Universitd di Catania, Viale A. Doria 6, 95125 Catania, Italy;

Dipartimento di Chimica Organica e Biologica, Universita di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina, Italy;

Dipartimento di Scienze Chimiche, Universitd di Catania, Viale A. Doria 6, 95125 Catania, Italy;

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专利

1. A non-covalent assembly for electron transfer based on a calixarene-porphyrin conjugate: tweezers for a quinone [J] . Arimura T., Sugihara H., Murata S., New Journal of Chemistry . 1999,第10期

机译：基于杯芳烃-卟啉共轭物的非共价电子转移组件：镊子
2. A non-covalent assembly for electron transfer based on a calixarene-porphyrin conjugate:tweezers for a quinone [J] . Arimura Takashi, Ide Seiji New Journal of Chemistry . 1999,第1期

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3. Mixed ligand ruthenium(II) complexes of bis(pyrDE-2-yl)-/bis(benzimDEazol-2-yl)-dithioether and diimines: Study of non-covalent DNA binding and cytotoxicity [J] . Rajendiran V, Murali M, Suresh E, Dalton transactions: An international journal of inorganic chemistry . 2008,第1期

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4. A Non-dominated Sorting Approach to Bi-objective Optimisation of Mixed-Model Two-Sided Assembly Lines [C] . Ibrahim Kucukkoc International conference on large-scale scientific computing . 2018

机译：混合模型两面流水线双目标优化的非支配排序方法
5. The study of molecular assemblies formed via non-covalent interactions between calixarenes. [D] . Lee, Eun-Ju. 2003

机译：对杯芳烃之间非共价相互作用形成的分子组装的研究。
6. Competitive chiral induction in a 2D molecular assembly: Intrinsic chirality versus coadsorber-induced chirality [O] . Ting Chen, Shu-Ying Li, Dong Wang, 2017

机译：二维分子组装中的竞争性手性诱导：本征手性与助吸附剂诱导的手性
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机译：2D分子组装中的竞争性手性诱导：内在手性与共富人诱导的手性

Induction of chirality in porphyrin-(bis)calixarene assemblies: a mixed covalent-non-covalent vs a fully non-covalent approach

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