Electrophilic fluorination of cationic Pt-aryl complexes

Shu-Bin Zhao; Rui-Yao Wang; Ha Nguyen; Jennifer J. Becker; Michel R. Gagne

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Electrophilic fluorination of cationic Pt-aryl complexes

机译：阳离子Pt-芳基配合物的亲电氟化

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摘要

The electrophilic fluorination of several (triphos)Pt-aryl~+ establishes the first example of aryl-F coupling from a Pt center.

机译：几个（triphos）Pt-芳基+的亲电氟化建立了一个从Pt中心进行芳基-F偶联的第一个例子。

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《Chemical Communications》 |2012年第3期|p.443-445|共3页
作者
Shu-Bin Zhao; Rui-Yao Wang; Ha Nguyen; Jennifer J. Becker; Michel R. Gagne;
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作者单位

Caudill Laboratories, Department of Chemistry,University of North Carolina at Chapel Hill, Chapel Hill,NC 27599-3290, USA;

Department of Chemistry, Queen's University, Kingston,ON K7L 3N6, Canada;

Caudill Laboratories, Department of Chemistry,University of North Carolina at Chapel Hill, Chapel Hill,NC 27599-3290, USA;

U.S. Army Research Office, P.O. Box 12211,Research Triangle Park, NC 27709, USA;

Caudill Laboratories, Department of Chemistry,University of North Carolina at Chapel Hill, Chapel Hill,NC 27599-3290, USA;

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1. Cationic tridium-perfluoroalkyl complexes with NH3 and PH3 ligands. Activation of carbon-fluorine bonds by H2S to give bis(trifluoromethyl)dithiametallacyclobutane and bis(trifluoromethyl)trithiametallacyclohexane complexes [J] . Hughes RP., Smith JM., Incarvito CD., Organometallics . 2002,第10期

机译：具有NH3和PH3配体的阳离子三氟全氟烷基络合物。 H2S活化碳-氟键，生成双（三氟甲基）二硫杂金属环丁烷和双（三氟甲基）三硫杂金属环己烷络合物
2. Outer-Sphere Electrophilic Fluorination of Organometallic Complexes [J] . Lucy M. Milner, Natalie E. Pridmore, Adrian C. Whitwood, Journal of the American Chemical Society . 2015,第33期

机译：有机金属配合物的外球亲电氟化
3. Electrophilic fluorination of group 10 organometallic complexes: Chemistry beyond oxidative addition [J] . Vigalok A. Organometallics . 2011,第18期

机译：第10组有机金属配合物的亲电子氟化：氧化加成以外的化学
4. CATALYTIC ENANTIOSELECTIVE TANDEM CONJUGATE ADDITION / ELECTROPHILIC FLUORINATION FOR THE CONSTRUCTION OF CHIRAL FLUORINE - CONTAINING BUILDING BLOCKS [C] . Wang Liang, Cui Hangfeng, Nie Jing, Treatise Gist Anthology . 2007

机译：催化对映体串联共轭加/电泳合成手性含氟砌块建筑。
5. Organometallics in superacidic media: Generation of highly electrophilic cationic (fluoroalkyl)phosphine platinum (II) complexes. [D] . Houlis, James F. 2001

机译：超酸性介质中的有机金属：生成高度亲电的阳离子（氟代烷基）膦铂（II）配合物。
6. Electrophilic fluorination of cationic Pt-aryl complexes [O] . Shu-Bin Zhao, Rui-Yao Wang, Ha Nguyen, -1

机译：阳离子铂 - 芳基配合物的电氟化
7. Cationic Iridium−Perfluoroalkyl Complexes with NH3and PH3Ligands. Activation of Carbon−Fluorine Bonds by H2S To Give Bis(trifluoromethyl)dithiametallacyclobutane and Bis(trifluoromethyl)trithiametallacyclohexane Complexes [O] . Russell P. Hughes, Jeremy M. Smith, Christopher D. Incarvito, 2004

机译：阳离子铱 - 全氟烷基配合物与NH3和Ph3ligands。通过H 2 S活化碳氟键，得到双（三氟甲基）二甲基碳酸丁烷和双（三氟甲基）三碱基己烷配合物

Electrophilic fluorination of cationic Pt-aryl complexes

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