Monitoring the on-off switching of the electronic communication in diethynylplatinum(Ⅱ)-bridged dyads using triplet energy transfer

Ahmed M. Soliman; Mohammed Abdelhameed; Eli Zysman-Colman; Pierre D. Harvey

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Monitoring the on-off switching of the electronic communication in diethynylplatinum(Ⅱ)-bridged dyads using triplet energy transfer

机译：利用三重态能量转移监测二乙炔铂（Ⅱ）-桥联二联体中电子通信的通断开关

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Despite conjugation and downhill manifolds in [Ir]-[Pt]-[ZnTPP] ([ZnTPP] = (tetraphenylporphyrin)zinc(Ⅱ), [Ir] = bis(phenylpyridinato)-(bipyridine)iridium(Ⅲ), [Pt] = trans-C≡CPt(PBu_3)_2-C≡C), essentially no T_1[lr] → S_1 /T_1[ZnTTP] energy transfer occurs.

机译：尽管在[Ir]-[Pt]-[ZnTPP]中存在共轭和下坡流形（[ZnTPP] =（四苯基卟啉）锌（Ⅱ），[Ir] =双（苯基吡啶并）-（联吡啶）铱（Ⅲ），[Pt] =反式-C≡CPt（PBu_3）_2-C≡C），基本上没有发生T_1 [lr]→S_1 / T_1 [ZnTTP]能量转移。

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《Chemical Communications》 |2013年第49期|5544-5546|共3页
作者
Ahmed M. Soliman; Mohammed Abdelhameed; Eli Zysman-Colman; Pierre D. Harvey;
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Department de Chimie, Universite de Sherbrooke, 2550 Boulevard de l'Universite,Sherbrooke, Quebec, Canada J1K 2R1;

Department de Chimie, Universite de Sherbrooke, 2550 Boulevard de l'Universite,Sherbrooke, Quebec, Canada J1K 2R1;

Department de Chimie, Universite de Sherbrooke, 2550 Boulevard de l'Universite,Sherbrooke, Quebec, Canada J1K 2R1;

Department de Chimie, Universite de Sherbrooke, 2550 Boulevard de l'Universite,Sherbrooke, Quebec, Canada J1K 2R1;

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Monitoring the on-off switching of the electronic communication in diethynylplatinum(Ⅱ)-bridged dyads using triplet energy transfer

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