Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group

Li Yan Chan; Sunggak Kim; Taekyu Ryu; Phil Ho Lee

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Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group

机译：使用新的单磷酸指导基团进行钯催化的芳基氢磷酸的正链烯基化

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摘要

A highly efficient Pd-catalyzed ortho-alkenylation is reported using a mono-phosphoric acid-directing group for the first time. This phosphoric acid-directing group is successfully utilized for the synthesis of various alkenylated products and offers a new approach to transition-metal-catalyzed C-H activation.

机译：首次报道了使用单磷酸定向基团的高效钯催化的邻烯基化反应。该磷酸定向基团已成功用于各种烯基化产物的合成，并为过渡金属催化的C-H活化提供了一种新方法。

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《Chemical Communications》 |2013年第41期|4682-4684|共3页
作者
Li Yan Chan; Sunggak Kim; Taekyu Ryu; Phil Ho Lee;
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作者单位

Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore;

Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore;

Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea;

Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea;

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Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group

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