Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

Taniyuki Furuyama; Mitsuo Asai; Nagao Kobayashi

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Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

机译：通过改变其轴向配体来控制四氮杂卟啉第15族配合物的吸收特性

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摘要

Tetraazaporphyrin (TAP) complexes with group 15 elements (phosphorus(Ⅴ) or arsenic(Ⅴ)) containing two axial OH ligands showed reversible spectroscopic changes with acid or base doping. Spectroscopic and theoretical analysis revealed that the modification of axial ligands can tune the interaction between peripheral substituents and the TAP macrocycle.

机译：具有两个轴向OH配体的15组元素（磷（Ⅴ）或砷（Ⅴ））的四氮杂卟啉（TAP）配合物在酸或碱掺杂下可逆光谱变化。光谱和理论分析表明，轴向配体的修饰可以调节外围取代基和TAP大环之间的相互作用。

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《Chemical Communications》 |2014年第95期|15101-15104|共4页
作者
Taniyuki Furuyama; Mitsuo Asai; Nagao Kobayashi;
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作者单位

Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan;

Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan;

Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan;

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Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

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