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Layered structures and nanosheets of pyrimidinethiolate coordination polymers

机译:嘧啶硫醇盐配位聚合物的层状结构和纳米片

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摘要

We report the synthesis, crystal structure and exfoliation of a new member of an important family of layered compounds: lamellar pyrimidinethiolate coordination polymers. Conductivity measurements and DFT calculations of iron(Ⅱ) pyrimidine-2-thiolate show that this material and a related compound are insulators.
机译:我们报告了重要的层状化合物家族的新成员的合成,晶体结构和剥落:层状嘧啶硫醇盐配位聚合物。嘧啶-2-硫代铁(Ⅱ)的电导率测量和DFT计算表明该材料及相关化合物为绝缘体。

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  • 来源
    《Chemical Communications》 |2014年第30期|3955-3957|共3页
  • 作者单位

    Materials Science & Metallurgy, University of Cambridge, CB3 OFS, UK;

    Materials Science & Metallurgy, University of Cambridge, CB3 OFS, UK,International Center for Materials Nanoarchitectonics (WPI-MANA),National Institute for Materials Science (NIMS), Ibaraki 305-0044, Japan;

    S.N. Bose National Centre for Basic Sciences, Block-JD, Salt Lake,Kolkata 700098, India;

    S.N. Bose National Centre for Basic Sciences, Block-JD, Salt Lake,Kolkata 700098, India;

    Materials Science & Metallurgy, University of Cambridge, CB3 OFS, UK;

    Materials Science & Metallurgy, University of Cambridge, CB3 OFS, UK;

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