Reaction of gold(Ⅲ) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF_6]. Crystal structure of [Au(bipy~(ip))(η~2-CH_2=CHPh)][PF_6] (hipy~(ip) = 6-isopropyl-2,2′-bipyridine)

Maria A. Cinellu; Giovanni Minghetti; Sergio Stoccoro; Antonio Zucca; Mario Manassero

首页> 外文期刊>Chemical Communications >Reaction of gold(Ⅲ) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF_6]. Crystal structure of [Au(bipy~(ip))(η~2-CH_2=CHPh)][PF_6] (hipy~(ip) = 6-isopropyl-2,2′-bipyridine)

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Reaction of gold(Ⅲ) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF_6]. Crystal structure of [Au(bipy~(ip))(η~2-CH_2=CHPh)][PF_6] (hipy~(ip) = 6-isopropyl-2,2′-bipyridine)

机译：金（Ⅲ）氧配合物与烯烃的反应。前所未有的金烯烃复合物[Au（N，N）（烯烃）] [PF_6]的合成。 [Au（bipy〜（ip））（η〜2-CH_2 = CHPh）] [PF_6]（hipy〜（ip）= 6-异丙基-2,2'-联吡啶）的晶体结构

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Gold alkene complexes [Au(bipy~R)(η~2-alkene)][PF_6] (bipy~R = 6-alkyl-2,2′-bipyridine) have been obtained by reaction of gold(Ⅲ) oxo complexes [Au_2(bipy~R)_2(μ-O)_2][PF_6]_2 with alkenes. The crystal structure of the styrene adduct [Au(bipy~(ip))(η~2-CH_2=CHPh)][PF_6] (bipy~(ip) = 6-isopropyl-2,2′-bipyridine) has been solved by X-ray analysis.

机译：通过金（Ⅲ）氧代配合物的反应获得了金烯配合物[Au（bipy〜R）（η〜2-链烯）] [PF_6]（bipy〜R = 6-烷基-2,2'-联吡啶）[ Au_2（bipy〜R）_2（μ-O）_2] [PF_6] _2和烯烃。苯乙烯加合物[Au（bipy〜（ip））（η〜2-CH_2 = CHPh）] [PF_6]（bipy〜（ip）= 6-异丙基-2,2'-联吡啶）的晶体结构已解析通过X射线分析。

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来源
《Chemical Communications》 |2004年第14期|p.1618-1619|共2页
作者
Maria A. Cinellu; Giovanni Minghetti; Sergio Stoccoro; Antonio Zucca; Mario Manassero;
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Dipartimento di Chimica, Universita di Sassari, via Vienna 2, I-07100 Sassari, Italy;

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5. Reactions of Gold(III) Complexes With Alkenes in Aqueous Solution -- Formation of beta-hydroxyalkylgold(III) Complexes. [D] . Rezsnyak, Chad E. 2012

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Reaction of gold(Ⅲ) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF_6]. Crystal structure of [Au(bipy~(ip))(η~2-CH_2=CHPh)][PF_6] (hipy~(ip) = 6-isopropyl-2,2′-bipyridine)

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