Synthesis of novel dendrimer-like star block copolymers with definite numbers of arms by combination of ROP and ATRP

Youliang Zhao; Xintao Shuai; Chuanfu Chen; Fu Xi

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Synthesis of novel dendrimer-like star block copolymers with definite numbers of arms by combination of ROP and ATRP

机译：ROP和ATRP结合合成具有支臂数的新型树状大分子星形嵌段共聚物

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摘要

Well-defined biodegradable dendrimer-like star block copolymers with up to 24 arms were successfully synthesized by combination of living ring-opening polymerization (ROP) and atom transfer radical polymerization (ATRP) on the basis of dendritic benzyl alcohols.

机译：在树状苄醇的基础上，通过活性开环聚合（ROP）和原子转移自由基聚合（ATRP）的组合，成功合成了多达24个支链的生物定义清晰的树状聚合物状星形嵌段共聚物。

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《Chemical Communications》 |2004年第14期|p. 1608-1609|共2页
作者
Youliang Zhao; Xintao Shuai; Chuanfu Chen; Fu Xi;
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作者单位

State Key Laboratory of Polymer Physics & Chemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China;

State Key Laboratory of Polymer Physics & Chemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China;

State Key Laboratory of Polymer Physics & Chemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China;

State Key Laboratory of Polymer Physics & Chemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China;

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正文语种 eng
中图分类化学;
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1. Synthesis and Characterization of Novel Resorcinarene-Centered Amphiphilic Star-Block Copolymers Consisting of Eight ABA Triblock Arms by Combination of ROP, ATRP, and Click Chemistry [J] . Gou PF, Zhu WP, Zhu N, Journal of Polymer Science, Part A. Polymer Chemistry . 2009,第11期

机译：ROP，ATRP和点击化学的结合，由八种ABA三嵌段臂组成的新型以间苯二烯为中心的两亲性星型嵌段共聚物的合成与表征
2. Synthesis of ABC miktoarm star block copolymers from a new heterotrifunctional initiator by combination of ATRP and ROP [J] . Claudia Gordin, Christelle Delaite, Hussein Medlej Polymer bulletin . 2009,第6期

机译：由ATRP和ROP结合的新型异三官能引发剂合成ABC拟星形嵌段共聚物。
3. Block and star block copolymers by mechanism transformation. VIII Synthesis and characterization of triblock poly (LLA-b-St-b-MMA) by combination of ATRP and ROP [J] . Lei Tao, Bin Luan, Cai-yuan Pan Polymer: The International Journal for the Science and Technology of Polymers . 2003,第4期

机译：嵌段和星形嵌段共聚物通过机理转变。 VIII通过ATRP和ROP结合制备三嵌段聚（LLA-b-St-b-MMA）并进行表征
4. Synthesis of PCL-PS Star-Block Copolymer by Combination of Lipase-Catalyzed Ring-Opening Polymerization and ATRP [C] . Ruixue Liu, Yan Shi, Zhjfeng Fu Asian International Conference on Advanced Materials . 2006

机译：通过脂肪酶催化的开环聚合和ATRP组合合成PCL-PS星嵌段共聚物
5. Synthesis of amphiphilic heteroarm star block copolymers and effect of their architecture on micellar properties. [D] . Yun, Jongpil. 2003

机译：两性杂臂星形嵌段共聚物的合成及其结构对胶束性能的影响。
6. One-Pot Synthesis of Star Copolymers by the Combination of Metal-Free ATRP and ROP Processes [O] . Gorkem Yilmaz 2019

机译：无金属ATRP和ROP结合一锅合成星形共聚物
7. Novel Temperature/Reduction Dual-Stimulus Responsive Triblock Copolymer P(MEO2MA-co- OEGMA)-b-PLLA-SS-PLLA-b-P(MEO2MA-co-OEGMA) via a Combination of ROP and ATRP: Synthesis, Characterization and Application of Self-Assembled Micelles [O] . Fei Song, Zhidan Wang, Wenli Gao, 2020

机译：通过ROP和ATRP的组合：合成，表征和应用，新型温度/抑制双刺激响应三嵌段共聚物P（MeO2mA-Co-Cogma）-B-PLLA-SS-PLLA-BP（MEO2MA-CO-oegma）自组装胶束

Synthesis of novel dendrimer-like star block copolymers with definite numbers of arms by combination of ROP and ATRP

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