The elusive phosphorescence of pyrromethene-BF2 dyes revealed in new multicomponent species containing Ru(II)-terpyridine subunits

Galletta M; Campagna S; Quesada M; Ulrich G; Ziessel R

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The elusive phosphorescence of pyrromethene-BF2 dyes revealed in new multicomponent species containing Ru(II)-terpyridine subunits

机译：含有Ru（II）-吡啶基亚基的新型多组分物质揭示了吡咯亚甲基-BF2染料的难以捉摸的磷光

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摘要

The triplet emitting state of an indacene at 774 nm ( of 50 ms life-time) was observed for the first time in new ruthenium(II) complexes based on bipartite ligands carrying one or two indacene subunits linked via phenylethynyl connectors to terpyridine fragments.

机译：在新的钌（II）络合物中，首次发现了茚并三聚体在774 nm处的三重态发射态，该络合物是基于二配体配体，该配体带有一个或两个通过苯乙炔基连接器连接到三联吡啶片段上的茚并亚基。

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来源
《Chemical Communications》 |2005年第33期|p. 4222-4224|共3页
作者
Galletta M; Campagna S; Quesada M; Ulrich G; Ziessel R;
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作者单位

Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
COORDINATION-COMPLEXES; CHARGE-TRANSFER; EXCITED-STATES; BORADIAZAINDACENE; PHOTOCHEMISTRY; LUMINESCENT; TERPYRIDINE; PROBES; METAL;

机译：配位化合物;电荷转移;激发态;硼氮杂多烯;光化学;发光;萜啶;问题;金属;

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1. Bdmpp complexes of Ru(II) as structural analogs for Ru(II)-2,2':6',2"-terpyridine species (where bdmpp is 2,6-bis(3.5-dimethyl-N-pyrazoyl)pyridine) [J] . Vincent J. Catalano, Raif Kurtaran, Ryan A. Keck, Inorganica Chimica Acta . 1999,第2期

机译：Ru（II）的Bdmpp络合物作为Ru（II）-2,2'：6'，2“-吡啶类化合物的结构类似物（其中bdmpp是2,6-双（3.5-二甲基-N-吡唑酰基）吡啶）
2. End-Functionalization of Semiconducting Species with Dendronized Terpyridine-Ru(II)-Terpyridine Complexes [J] . Pefkianakis EK, Tzanetos NP, Chochos CL, Journal of Polymer Science, Part A. Polymer Chemistry . 2009,第7期

机译：半导体物种的末端官能化与Dendronized Terpyridine-Ru（II）-Terpyridine配合物
3. Terpyridine Zn(II),Ru(III),and Ir(III) Complexes:The Relevant Role of the Nature of the Metal Ion and of the Ancillary Ligands on the Second-Order Nonlinear Response of Terpyridines Carrying Electron Donor or Electron Acceptor Groups [J] . Francesca Tessore, Dominique Roberto, Renato Ugo, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第24期

机译：联吡啶Zn（II），Ru（III）和Ir（III）配合物：金属离子和辅助配体的性质对带有电子供体或电子受体基的联吡啶的二阶非线性响应的相关作用
4. Development of new efficient Ru dyes having β-diketonate and terpyridine ligands for solar cells [C] . Takeshi Yamaguchi, Naoyuki Shibayama, Makoto Nakade, Organic Photovoltaics VIII; Proceedings of SPIE-The International Society for Optical Engineering; vol.6656 . 2007

机译：具有β-二酮酸酯和三联吡啶配体的新型高效Ru染料的开发
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机译：为高效染料敏化太阳能电池调整新型Ru（II）聚吡啶基配合物的基态和激发态氧化电位。
6. Synthesis photophysical and electrochemical characterization of terpyridine-functionalized dendritic oligothiophenes and their Ru(II) complexes [O] . Amaresh Mishra, Elena Mena-Osteritz, Peter Bäuerle 2013

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The elusive phosphorescence of pyrromethene-BF2 dyes revealed in new multicomponent species containing Ru(II)-terpyridine subunits

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