Ru(Ⅳ)-catalyzed isomerization of allylamines in water: A highly efficient procedure for the deprotection of N-allylic amines

摘要

A general and efficient method for the deprotection of N-allylic substrates in aqueous media, using catalytic amounts of the bis(allyl)-ruthenium(Ⅳ) complexes [Ru(η~3 : η~3 : η~3-C_(12)H_(18))Cl_2] (1) and [{Ru(η~3 : η~3-C_(10)H_(16)(μ-Cl)Cl}_2] (2), has been developed.