Homoleptic uranium(III) imidodiphosphinochalcogenides including the first structurally characterised molecular trivalent actinide-Se bond

Andrew J. Gaunt; Brian L. Scott; Mary P. Neu

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Homoleptic uranium(III) imidodiphosphinochalcogenides including the first structurally characterised molecular trivalent actinide-Se bond

机译：均一的铀（III）亚氨基二膦基硫属元素化物，包括第一个结构上表征的分子三价act系元素-硒键

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摘要

Preparation of U[N(EPPh_2)_2]_3 (E = S or Se) by treating U[N(SiMe_3)_2]_3 with three equivalents of NH(EPPh_2)_2 is described together with presentation of a hitherto unreported molecular crystal structure containing An(III)-Se bonds (An = actinide).

机译：描述了通过用三当量的NH（EPPh_2）_2处理U [N（SiMe_3）_2] _3来制备U [N（EPPh_2）_2] _3（E = S或Se）的方法，并介绍了迄今为止尚未报道的分子晶体结构含有An（III）-Se键（An = in系元素）。

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来源
《Chemical Communications》 |2005年第25期|p.3215-3217|共3页
作者
Andrew J. Gaunt; Brian L. Scott; Mary P. Neu;
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作者单位

Actinide, Catalysis, and Separations Chemistry (C-SIC), Chemistry Division, Los Alamos National Laboratory, Mail Stop J-514, Los Alamos, New Mexico, 87545, USA;

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正文语种 eng
中图分类化学;
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Homoleptic uranium(III) imidodiphosphinochalcogenides including the first structurally characterised molecular trivalent actinide-Se bond

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