Regiospecific topochemical reactions controlled by trifluoromethyl directing groups

Liu J; Boarman KJ

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Regiospecific topochemical reactions controlled by trifluoromethyl directing groups

机译：三氟甲基指导基团控制的区域特异性拓扑化学反应

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A parallel, offset-stacked orientation was found in the crystal packing of E, E-1,4-di(o-trifluoromethyl) phenyl-1,3-butadiene. UV-irradiation of the powered crystalline sample resulted in a quantitative conversion to a single [ 2 + 2] cycloaddition product.

机译：在E，E-1，4-二（邻三氟甲基）苯基-1，3-丁二烯的晶体堆积中发现平行的，错位堆叠的取向。粉末状晶体样品的紫外线照射导致定量转化为单一的[2 + 2]环加成产物。

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来源
《Chemical Communications》 |2005年第3期|p. 340-341|共2页
作者
Liu J; Boarman KJ;
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作者单位

Murray State Univ, Dept Chem, Murray, KY 42071 USA;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
SOLID-STATE; STACKING INTERACTIONS; PHOTODIMERIZATION; CONSTRUCTION; REACTIVITY; CRYSTALS;

机译：固态;相互作用;光二聚化;结构;反应性;晶体;

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2. Regiospecific and diastereoselective aldol reaction of chiral N-sulfinyl metalloenamines with α,β-unsaturated trifluoromethyl ketones: Asymmetric synthesis of tertiary trifluoromethyl allylic carbinols [J] . Zhen-Jiang Liu, Fan Zhang, Jin-Tao Liu Journal of Fluorine Chemistry . 2012,第Null期

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Regiospecific topochemical reactions controlled by trifluoromethyl directing groups

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