An enantioselective desymmetrization approach to C9-substituted trans-hydrindene rings based on a diastereotopic group-selective intramolecular Diels-Alder reaction

Azzi N; Griffen E; Light M; Linclau B

首页> 外文期刊>Chemical Communications >An enantioselective desymmetrization approach to C9-substituted trans-hydrindene rings based on a diastereotopic group-selective intramolecular Diels-Alder reaction

【24h】

An enantioselective desymmetrization approach to C9-substituted trans-hydrindene rings based on a diastereotopic group-selective intramolecular Diels-Alder reaction

机译：基于非对映异构基团选择性分子内Diels-Alder反应的C9取代的反式-茚环的对映选择性去对称化方法

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The synthesis of an achiral skipped bis(1,3-diene) substrate was achieved, which was shown to undergo an enantioselective, diastereotopic group-selective, intramolecular Diels-Alder reaction.

机译：实现了非手性跳过的双（1,3-二烯）底物的合成，该底物显示出经历了对映选择性，非对映异构基团选择性，分子内Diels-Alder反应。

著录项

来源
《Chemical Communications》 |2006年第47期|p. 4909-4911|共3页
作者
Azzi N; Griffen E; Light M; Linclau B;
展开▼
作者单位

Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England;

AstraZeneca, Macclesfield SK10 4TG, Cheshire, England;

Xray Crystallog Ctr, Sch Chem, Southampton SO17 1BJ, Hants, England;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
NATURAL-PRODUCT SYNTHESIS; RIGHT-HAND HALF; 2-DIRECTIONAL SYNTHESIS; SYNTHETIC APPLICATIONS; STEREOCHEMICAL ASPECTS; DESYMMETRISATION; CYCLOADDITIONS; ANTIBIOTIC-X-14547A; DIASTEREOSELECTION; TRANSFORMATIONS;

机译：天然产物合成;右手半;2-方向合成;合成应用;立体化学方面;脱甲基化;循环载荷;抗生素X-14547A;非对映异构体选择;转化;

相似文献

外文文献
中文文献
专利

1. A new strategy in enantioselective intramolecular hetero Diels-alder reaction: catalytic double asymmetric induction during the tandem transetherificaton-intramolecular hetero Diels-alder reaction of methyl (E)-4-methoxy-2-oxo-3-butenoate with rac-6- [J] . Hidetaka Koga, Eiji Wada Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2003,第4期

机译：对映选择性分子内杂Diels-Alder反应的新策略：（E）-4-甲氧基-2-氧-3-丁烯酸甲酯与rac-6-的串联跨醚交换-分子内杂Diels-Alder反应过程中的催化双不对称诱导
2. A Convenient Approach to Polycyclic Derivatives with a cis-Fused 2,6-Dioxabicyclo[4.3.0]nonane System by the Sequence Ring-Opening/Intramolecular Ring-Closing Enyne Metathesis/Diels-Alder Reaction [J] . Aljarilla A, Murcia MC, Csaky AG, European journal of organic chemistry . 2009,第6期

机译：顺式开环/分子内封闭的烯炔复分解/ Diels-Alder反应的顺式2,6-二氧杂双环[4.3.0]壬烷体系多环衍生物的简便合成方法
3. A Stereoselective and Atom-Efficient Approach to Multifunctionalized Five- and Six-Membered Rings via a Novel Michael-Initiated Intramolecular Diels-Alder Furan Reaction [J] . Irishi N.N.Namboothiri, Madhu Ganesh, Shaikh M.Mobin, The Journal of Organic Chemistry . 2005,第6期

机译：通过新型迈克尔引发的分子内Diels-Alder Furan反应的多官能五元和六元环的立体选择性和原子高效方法
4. Enantioselective Reactions of Bicyclic Allylic Compounds Based on Desymmetrization of a Symmetrical Allylic Ligand Using Chiral Palladium Complexes. [C] . Ryohei Ogawa, Yusuke Shigemori, Koichi Uehara Symposium on Organometallic Chemistry . 2006

机译：双环烯丙基化合物基于使用手性钯配合物的对称烯丙基配体的脱水化合物的映选择性反应。
5. Synthetic applications of the type 2 intramolecular Diels-Alder reaction: (1) Efforts toward the total synthesis of the welwitindolinone alkaloids and (2) Enantioselective synthesis of bridged bicyclic ring systems. [D] . Brailsford, John A. 2009

机译：2型分子内Diels-Alder反应的合成应用：（1）努力实现welwitindolinone生物碱的全合成，以及（2）桥联双环系统的对映选择性合成。
6. Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates [O] . Weijun Yao, Xiaowei Dou, Shan Wen, -1

机译：通过烯丙酸酯的分子内Rauhut-Currier反应对环己二酮进行对映选择性去对称化
7. A Stereoselective and Atom-Efficient Approach to Multifunctionalized Five- and Six-Membered Rings via a Novel Michael-Initiated Intramolecular Diels-Alder Furan Reaction [O] . -1

机译：通过新的迈克尔发起的分子内Diels-Alder Furan反应，通过新的迈克尔发起的五元环的立体化和原子有效的方法

An enantioselective desymmetrization approach to C9-substituted trans-hydrindene rings based on a diastereotopic group-selective intramolecular Diels-Alder reaction

摘要

著录项

相似文献

相关主题

期刊订阅