Solvent-free, heterogeneous photooxygenation of hydrocarbons by Hyflon (R) membranes embedding a fluorous-tagged decatungstate

Carraro M; Gardan M; Scorrano G; Drioli E; Fontananova E; Bonchio M

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Solvent-free, heterogeneous photooxygenation of hydrocarbons by Hyflon (R) membranes embedding a fluorous-tagged decatungstate

机译：通过Hyflon（R）膜嵌入氟标记的十分解钨酸酯进行无溶剂的烃类异质光氧合

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摘要

Hybrid fluoropolymeric membranes with 25% loading of the fluorous-tagged (RfN)(4)W10O32 effect the solvent-free photooxygenation of benzylic C - H bonds with up to 6100 TONs in 4 hours.

机译：含氟标签（RfN）（4）W10O32的25％负载的杂化含氟聚合物膜可在4小时内实现高达6100 TON的苄基C H键的无溶剂光氧化。

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来源
《Chemical Communications》 |2006年第43期|p. 4533-4535|共3页
作者
Carraro M; Gardan M; Scorrano G; Drioli E; Fontananova E; Bonchio M;
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作者单位

ITM CNR, I-35131 Padua, Italy;

Univ Padua, Dept Chem Sci, I-35131 Padua, Italy;

Univ Calabria, ITM CNR, I-87030 Arcavacata Di Rende, CS, Italy;

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正文语种 eng
中图分类化学;
关键词
PHOTOCATALYTIC OXIDATION; AEROBIC PHOTOOXIDATION; OLEFIN EPOXIDATION; HYDROGEN-PEROXIDE; ORGANIC-COMPOUNDS; ELECTRON-TRANSFER; MOLECULAR-OXYGEN; EXCITED-STATE; WATER; CATALYSIS;

机译：光催化氧化;需氧光氧化;烯烃环氧氧化;过氧化氢;有机化合物;电子传递;分子氧;激发态;水;催化;

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1. Hybrid photocatalytic membranes embedding decatungstate for heterogeneous photooxygenation [J] . Marcella Bonchio, Mauro Carraro, Martino Gardan Topics in Catalysis . 2006,第1a4期

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2. Hybrid photocatalytic membranes embedding decatungstate for heterogeneous photooxygenation [J] . Marcella Bonchio, Mauro Carraro, Martino Gardan, Topics in Catalysis . 2006,第1a4期

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3. Hybrid Photocatalytic Membranes Embedding Decatungstate for Heterogeneous Photooxydation [J] . Enrica Fontananova, Enrico Drioli, Laura Donato Desalination: The International Journal on the Science and Technology of Desalting and Water Purification . 2006,第1a3期

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Solvent-free, heterogeneous photooxygenation of hydrocarbons by Hyflon (R) membranes embedding a fluorous-tagged decatungstate

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