Novel spin transition between S=5/2 and S=3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures

Ohgo Y; Chiba Y; Hashizume D; Uekusa H; Ozeki T; Nakamura M

首页> 外文期刊>Chemical Communications >Novel spin transition between S=5/2 and S=3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures

【24h】

Novel spin transition between S=5/2 and S=3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures

机译：在极低温度下高度鞍化的铁（III）卟啉配合物中S = 5/2和S = 3/2之间的新型自旋跃迁

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A novel spin transition between S=5/2 and S=3/2 has been observed for the first time in five-coordinate, highly saddled iron(III) porphyrinates by EPR and SQUID measurements at extremely low temperatures.

机译：通过极低温度下的EPR和SQUID测量，在五配位高鞍化卟啉铁（III）中首次观察到S = 5/2和S = 3/2之间的新型自旋跃迁。

著录项

来源
《Chemical Communications》 |2006年第18期|p. 1935-1937|共3页
作者
Ohgo Y; Chiba Y; Hashizume D; Uekusa H; Ozeki T; Nakamura M;
展开▼
作者单位

Toho Univ, Sch Med, Dept Chem, Ota Ku, Tokyo 1438540, Japan;

Toho Univ, Res Ctr Mat Integrated Properties, Funabashi, Chiba 2748510, Japan;

Toho Univ, Grad Sch Sci, Div Biomol Sci, Funabashi, Chiba 2748510, Japan;

RIKEN, Mol Characterizat Team, Wako, Saitama 3510198, Japan;

Tokyo Inst Technol, Dept Chem & Mat Sci, Tokyo 1528551, Japan;

Toho Univ, Grad Sch Sci, Div Chem, Funabashi, Chiba 2748510, Japan;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
MOLECULAR-STRUCTURE; STATE; PERCHLORATE; CROSSOVER; S=1/2; CORRPHYCENE; CRYSTAL;

机译：分子结构;状态;高氯酸盐;分枝;S = 1/2;异戊二烯;晶体;

相似文献

外文文献
中文文献
专利

1. Metal-porphyrin orbital interactions in highly saddled low-spin iron(III) porphyrin complexes [J] . Ohgo Y, Hoshino A, Okamura T, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第20期

机译：高鞍低旋铁（III）卟啉配合物中的金属卟啉轨道相互作用
2. Saddle-Shaped Six-Coordiante Iron(III) Porphyrin Complexes Showing a Novel Spin Crossover between S = 1/2 and S = 3/2 Spin States [J] . Takahisa Ikeue, Yoshiki Ohgo, Tatsuya Yamaguchi, Chembiochem: A European journal of chemical biology . 2001,第14期

机译：鞍形六坐标铁（III）卟啉复合物，显示在S = 1/2和S = 3/2旋转状态之间的新型旋转交叉
3. Anomalous Difference in Magnetic Behavior between Highly Saddled Iron(III) Porphyrin Complexes in the Solid State [J] . Yoshikio Ohgo, Takahisa Ikeue, Masashi Takahashi, European journal of inorganic chemistry . 2004,第4期

机译：固态高度鞍化的铁（III）卟啉配合物之间的磁行为异常差异
4. Spin States of Iron(III) in Highly Saddled Dodecaphenylporphyrin Complexes [C] . T. OHYA, J. TAKEDA, M. SATO International Conference on the Applications of the Mossbauer Effect . 2004

机译：铁（III）的旋转状态在高鞍十二烷基卟啉络合物中
5. IRON AND RUTHENIUM COMPLEXES POSSESSING UNUSUAL ELECTRONIC PROPERTIES. PART I: SYNTHESIS AND SPIN STATE STUDIES OF GAMMA-SUBSTITUTED TRIS(BETA-DIKETONATO)IRON(III) COMPLEXES AND THEIR BETA-KETOIMINE ANALOGUES DERIVED FROM TRIETHYLENETETRAMINE. PART II: A DIRECT MEASUREMENT OF DYNAMIC SPIN INTERCONVERSION RATES IN THE SPIN EQUILIBRIUM PROTEIN FERRIC MYOGLOBIN HYDROXIDE. PART III: SYNTHESIS, PHOTOEMISSION, AND ELECTROCHEMICAL STUDIES OF. [D] . DOSE, ERIC VON. 1978

机译：铁和钌络合物具有异常的电子特性。第一部分：γ-取代的三（三乙酮）铁（III）配合物及其三乙胺丁胺类似物的β-酮亚胺类似物的合成和自旋态研究。第二部分：纺丝平衡蛋白三水合肌红蛋白中动态纺丝互变速率的直接测量。第三部分：的合成，光生化和电化学研究。
6. Hydrogen-Bonding Interactions Trigger a Spin-Flip in Iron(III) Porphyrin Complexes [O] . Dipankar Sahoo, Matthew G Quesne, Sam P de Visser, -1

机译：氢键相互作用触发铁（III）卟啉配合物的自旋翻转
7. Metal-Porphyrin Orbital Interactions in Highly Saddled Low-Spin Iron(III) Porphyrin Complexes [O] . -1

机译：金属卟啉轨道轨道相互作用高鞍的低旋转铁（III）卟啉络合物
8. Reaction of Cyclohexene with Iodosylbenzene Catalyzed by Non-Porphyrin Complexesof Iron(III) and Aluminum(III). Newly Discovered Products and a New Mechanistic Proposal [R] . Yang, Y., Diederich, F., Valentine, J. S. 1990

机译：铁（III）和铝（III）非卟啉配合物催化环己烯与碘代苯的反应。新发现的产品和新的机械方案

Novel spin transition between S=5/2 and S=3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures

摘要

著录项

相似文献

相关主题

期刊订阅