Photoisomerization of cis,cis-1,4-diphenyl-1,3-butadiene in glassy media at 77 K: the bicycle-pedal mechanism

Saltiel J; Krishna TSR; Turek AM; Clark RJ

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Photoisomerization of cis,cis-1,4-diphenyl-1,3-butadiene in glassy media at 77 K: the bicycle-pedal mechanism

机译：顺式，顺式-1,4-二苯基-1,3-丁二烯在77 K玻璃介质中的光异构化：自行车踏板机理

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摘要

The cis-trans photoisomerization of cis,cis-1,4-diphenyl-1,3-butadiene in a soft isopentane glass at 77 K gives significant two-bond photoisomerization in contrast to solution and hard glassy media where only one-bond photoisomerization takes place.

机译：在溶液和硬玻璃介质中，仅需单键光致异构化的溶液和硬质玻璃介质，在77 K的软异戊烷玻璃中，顺式，顺式-1,4-二苯基-1,3-丁二烯的顺式-反式光致异构化可产生明显的双键光致异构化。地点。

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来源
《Chemical Communications》 |2006年第14期|p. 1506-1508|共3页
作者
Saltiel J; Krishna TSR; Turek AM; Clark RJ;
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作者单位

Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA;

Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
ELECTRONIC-STRUCTURE CALCULATIONS; HULA-TWIST PHOTOISOMERIZATION; RESONANCE RAMAN-SPECTRA; TRANS-1-(2-NAPHTHYL)-2-PHENYLETHENE CONFORMERS; PHOTOCHEMICAL-REACTION; TEMPERATURE; POLYENES; FLUORESCENCE; ABSORPTION; STATE;

机译：电子结构计算;呼拉扭曲光异构化;共振拉曼光谱;反式-1-（2-萘基）-2-苯乙烯;光化学反应;温度;聚合物;荧光;吸收;状态;

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1. Photoisomerization of cis,cis-and cis,trans-l,4-Di-o-tolyl-1,3-butadiene in Glassy Media at 77 K:One-Bond-Twist and Bicycle-Pedal Mechanisms [J] . Jack Saltiel, Michael A.Bremer, Somchoke Laohhasurayotin Angewandte Chemie . 2008,第7期

机译：顺式，顺式和顺式，反式-1,4-二-邻甲苯基-1,3-丁二烯在玻璃介质中在77 K下的光异构化：单键扭曲和自行车踏板机理
2. Photoisomerization of cis,cis-1,4-Diphenyl-1,3-butadiene in the Solid State:The Bicycle-Pedal Mechanism [J] . Jack Saltiel, Tallapragada S.R.Krishna, Ronald J.Clark The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2006,第5期

机译：固态顺式，顺式-1,4-二苯基-1,3-丁二烯的光异构化：自行车踏板机理
3. The photoisomerization of cis,trans-1,2-dideuterio-1,4-diphenyl-1,3-butadiene in solution. No bicycle-pedal [J] . Saltiel Jack, Redwood Christopher E., Kumar Ratheesh V. K. Photochemical & photobiological sciences: the official journal of the European Photochemistry Association and the European Society for Photobiology . 2019,第9期

机译：溶液中CIS，TRAS-1,2-替代二萜-1,4-二苯基-1,3-丁二烯的光硅酸化。没有自行车踏板
4. Aerobic and anaerobic bioremediation of cis-1, 2-dichloroethene and vinyl chloride [C] . Thomas S.Cornuet, Craig Sandefur, W.Mark Eliason, International conference on remediation of chlorinated and recalcitrant compounds . 2000

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5. Dual mechanisms for sgRNA3a-mediated recombination with genomic RNA3 of brome mosaic bromovirus: The role of cis-acting motifs and viral coat protein. [D] . Sztuba-Solinska, Joanna. 2011

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6. Identification of Poly(cis-1,4-Isoprene) Degradation Intermediates during Growth of Moderately Thermophilic Actinomycetes on Rubber and Cloning of a Functional lcp Homologue from Nocardia farcinica Strain E1 [O] . Ebaid M. A. Ibrahim, Matthias Arenskötter, Heinrich Luftmann, 1976

机译：橡胶中温嗜热放线菌生长过程中聚（顺1,4-异戊二烯）降解中间体的鉴定以及诺卡氏菌菌株E1的功能性lcp同源物的克隆
7. The Mechanics of the Bicycle Pedal Photoisomerization in Crystalline cis,cis-1,4-Diphenyl-1,3-butadiene [O] . -1

机译：结晶顺式的自行车踏板光学机制，顺式-1,4-二苯基-1,3-丁二烯
8. Addition of Dichlorocarbene to cis-1,4-poly(2-Trimethylsilylmethyl-1,3-Butadiene) Fluoride Catalyzed Elimination of Trimethylchlorosilane from cis-1,4-poly(2,3-Dichloromethylene-2-Trimethylsilymethyl-1,3- Butadiene). [R] . Jiang, W., Ding, Y. X., Weber, W. P. 1989

机译：向顺式-1,4-聚（2-三甲基甲硅烷基甲基-1,3-丁二烯）氟化物中加入二氯卡宾催化从顺式-1,4-聚（2,3-二氯亚甲基-2-三甲基甲硅烷基甲基-1,3-）中消除三甲基氯硅烷丁二烯）。

Photoisomerization of cis,cis-1,4-diphenyl-1,3-butadiene in glassy media at 77 K: the bicycle-pedal mechanism

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