Halocarbons in the marine atmosphere and surface seawater of the south Yellow Sea during spring

摘要

The concentrations of eight halocarbons, including methyl chloride (CH_3Cl), methyl bromide (CH_3Br), trichloroethene (C_2HCl_3), tetrachloroethene (C_2Cl_4), methyl chloroform (CH_3CCl_3), and three chloro-fluorocarbons (CFCs) (CFC-11, CFC-113, and CFC-114), were measured using a canister sampling technique and an automated preconcentration gas chromatograph-mass spectrometer system in the marine atmosphere of the south Yellow Sea (SYS) in May 2012. The atmospheric concentrations of these halocarbons ranged from single digits to hundreds of pptv. Our results revealed elevated regional mixing ratios for most halocarbons (particularly C_2HCl_3 and C_2Cl_4) compared with the levels found in literature, thus suggesting substantial releases of C_2HCl_3 and C_2Cl_4 from anthropogenic sources in China. By contrast, the mean concentration of CFC-11 in the present study was lower than the global average value. The diffusion and transportation of terrestrial pollutants from coastal areas are important sources of halocarbons in the SYS, whilst terrestrial sources contribute to elevated concentrations of the selected halocarbons in coastal water. The sea-to-air fluxes of CH_3Cl and CH_3Br were estimated based on the simultaneous measurement of the atmospheric and seawater concentrations of these two gases. By simple extrapolation, the emissions of CH_3Cl and CH_3Br from the study area could account for 0.04% and 3% of the global oceanic emissions, respectively, thus indicating that the coastal area constituted important sources of atmospheric CH_3Cl and CH_3Br.