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Preparation of the nickel foam/Ni-Ce-Co-O film electrode by thermal decomposition for oxygen evolution reaction

机译:通过热分解制氧泡沫反应制备泡沫镍/ Ni-Ce-Co-O薄膜电极

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摘要

The Ni-Ce-Co-O film on nickel foam was prepared by thermal decomposition of acetates. The electrochemical activity of the film was affected by the temperature of thermal decomposition. Cerium ions introduced into the oxide film could increase the surface area and improve the oxygen evolution reaction (OER) activity of the electrode. Compared with thermal decomposition of nitrates, the OER activity of the film prepared with acetates was higher. When the nickel foam/Ni-Ce-Co-O film electrode prepared with acetates was used as the anode, in 30% KOH solution (88 ± 2 ℃) at the current density of 4000 A/m~2, the cell voltage was 250 mV lower than that of the nickel foam anode. Furthermore, the film electrode exhibited good stability.
机译:通过乙酸盐的热分解制备镍泡沫上的Ni-Ce-Co-O膜。膜的电化学活性受热分解温度的影响。引入到氧化膜中的铈离子可以增加表面积并改善电极的氧释放反应(OER)活性。与硝酸盐的热分解相比,用乙酸盐制备的薄膜的OER活性更高。当用醋酸盐制备的泡沫镍/ Ni-Ce-Co-O薄膜电极为阳极时,在30%KOH溶液(88±2℃)中,电流密度为4000 A / m〜2,电池电压为比泡沫镍阳极低250 mV。此外,膜电极表现出良好的稳定性。

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