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Growth Of Fullerene On Ag And Hydrogen-passivated Si Substrates: Effect Of Electron Beam Exposure On Growth Modes

机译:在Ag和氢钝化的Si衬底上富勒烯的生长:电子束暴露对生长方式的影响

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We have used Auger electron spectroscopy (AES) to investigate the effect of electron beam exposure on growth modes of fullerene (C_(60)) on substrates like Ag and hydrogen-passivated Si(111). The electron beam comprises of 3.4 keV electrons, which are used in the AES study. To investigate the effect, Auger signal (AS) vs. deposition time (t) measurements were conducted in a sequential mode, i.e., alternating deposition of C_(60) and analysis using the electron beam. Duration of AES data collection after each deposition was the duration of exposure to electron beam in this experiment. For the growth study of C_(60) on Ag, three AS-t plots were recorded for three different durations of exposure to electron beam. Changes in the AS-t plot, depending on the duration of exposure to the electron beam, reflect the electron beam-induced damage. Electron beam-induced damages of C_(60) produce carbon materials of different densities and consequently transmission coefficient (α) of Auger electron through : this material changes. In order to fit the AES (AS vs. t) data a model has been used which simultaneously provides the growth mode and the transmission coefficient. Observation of an increasing transmission coefficient with the increasing duration of exposure to the electron beam from α = 0.34 to 0.60 indicates the change of the nature of the carbon material due to the partial damage of C_(60).
机译:我们已经使用俄歇电子能谱(AES)来研究电子束曝光对诸如Ag和氢钝化Si(111)之类的衬底上富勒烯(C_(60))的生长模式的影响。电子束包含3.4 keV电子,用于AES研究。为了研究这种效果,以顺序模式进行了俄歇信号(AS)与沉积时间(t)的测量,即交替沉积C_(60)并使用电子束进行分析。每次沉积后AES数据收集的持续时间就是本实验中电子束的暴露持续时间。为了研究C_(60)在Ag上的生长,在三个不同的电子束暴露时间下记录了三个AS-t图。根据暴露于电子束的持续时间,AS-t图的变化反映了电子束引起的损坏。电子束对C_(60)的破坏会产生不同密度的碳材料,从而通过以下方式产生俄歇电子的透射系数(α):该材料会发生变化。为了拟合AES(AS vs. t)数据,使用了一个模型,该模型同时提供增长模式和传输系数。随着电子束的暴露持续时间从α= 0.34到0.60的增加,观察到透射系数增加,这表明由于C_(60)的部分破坏,碳材料的性质发生了变化。

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