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A fluorescent probe for zinc detection based on organically functionalized SBA-15

机译:基于有机功能化SBA-15的锌检测荧光探针

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摘要

In this study, highly ordered mesoporous silica material (SBA-15) functionalized with N-(quinoline-8-yl)-2-(3-triethoxysilyl-propylamino)-acetamide (QTPA) as zinc probe has been reported. The anchoring to the surface of the SBA-15 was carried out by the reaction between the precursor and the hydroxyl groups available on the inner surface of the support. The primary ordered mesoporous structure of SBA-15 was well preserved after the grafting procedure. Fluorescence characterization showed that the obtained organic-inorganic hybrid composite displayed highly selective and sensitive to Zn~(2+) ion over other cations such as Cd~(2+), Pb~(2+), Ni~(2+) and Co~(2+). And the hybrid material has ideal chemical and spectroscopic properties for further biological and environmental applications.
机译:在这项研究中,已经报道了用N-(喹啉-8-基)-2-(3-三乙氧基甲硅烷基-丙基氨基)-乙酰胺(QTPA)功能化的高度有序的介孔二氧化硅材料(SBA-15)作为锌探针。通过前体与载体内表面上可利用的羟基之间的反应,将SBA-15表面锚定。 SBA-15的一级有序介孔结构在接枝过程后得到了很好的保留。荧光表征表明,所获得的有机-无机杂化复合材料对Zn〜(2+)离子具有较高的选择性,并且对Cd〜(2 +),Pb〜(2 +),Ni〜(2+), Co〜(2+)。杂化材料具有理想的化学和光谱性质,可用于进一步的生物学和环境应用。

著录项

  • 来源
    《Applied Surface Science》 |2010年第3期|p.802-806|共5页
  • 作者单位

    College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China;

    College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China;

    College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China;

    College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China;

    College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China;

    College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China;

    College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    fluorescent probe; SBA-15; zinc detection; functionalization;

    机译:荧光探针SBA-15;锌检测功能化;

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