Porous HKUST-1 derived CuO/Cu_2O shell wrapped Cu(OH)_2 derived CuO/ Cu_2O core nanowire arrays for electrochemical nonenzymatic glucose sensors with ultrahigh sensitivity

摘要

Self-supported CuO/Cu2O@CuO/Cu2O core-shell nanowire arrays (NWAs) are successfully fabricated by a simple and efficient method in this paper. Anodized Cu(OH)(2) NWAs could in-situ convert to HKUST-1 at room temperature easily. Cu(OH)(2) NWAs cores and HKUST-1 shells transform into CuO/Cu2O simultaneously after calcinations and form CuO/Cu2O@CuO/Cu2O core-shell NWAs. This smart configuration of the core-shell structure not only avoids the agglomeration of the traditional MOF-derived materials in particle-shape, but also facilitates the ion diffusion and increases the active sites. This novel structure is employed as substrate to construct nonenzymatic glucose sensors. The results indicate that glucose sensor based on CuO/Cu2O@CuO/Cu2O core-shell NWAs presents ultrahigh sensitivity (10,090 lA mM(-1) cm(-2)), low detection limit (0.48 lM) and wide linear range (0.99-1,330 lM). In addition, it also shows excellent anti-interference ability toward uric acid, ascorbic acid and L-Cysteine co-existing with glucose, good reproducibility and superior ability of real sample analysis. (C) 2018 Elsevier B.V. All rights reserved.