Modulation of current-time traces by two-pore arrangements of polyimide nanofluidic diodes

摘要

Liquid state arrangements of two polymeric membranes with single conical nanopores constitute nanofluidic diodes that allow a rich electrical functionality based on the modulation of individual conductances in aqueous electrolyte solutions. In particular, the prescribed sequences of current-time traces can be obtained by preprogramed switching between series and parallel pore connection arrangements. Hybrid nanopore-solid-state circuits are also possible. The basic applied physics of the nanofluidic diode arrangements can be understood from simple circuit theory concepts and should be of widespread interest to sensing and actuating procedures, controlled release dispensers, and energy conversion modules based on electrochemical signals.