Efficient enhancement of hydrogen production by Ag/Cu_2O/ZnO tandem triple-junction photoelectrochemical cell

摘要

Highly efficient semiconductor photoelectrodes for solar hydrogen production through photocatalytic water splitting are a promising and challenge solution to solve the energy problems. In this work, Ag/Cu_2O/ZnO tandem triple-junction photoelectrode was designed and prepared. An increase of 11 times of photocurrent is achieved in the Ag/Cu_2O/ZnO photoelectrode comparing to that of the Cu_2O film. The high performance of the Ag/Cu_2O/ZnO film is due to the optimized design of the tandem triple-junction structure, where the localized surface Plasmon resonance of Ag and the hetero-junctions efficiently absorb solar energy, produce, and separate electron-hole pairs in the photoca-thode.