An Ultraviolet–Visible and Near-Infrared-Responded Broadband NIR Phosphor and Its NIR Spectroscopy Application

摘要

High-radiance near-infrared (NIR) phosphor-converted light-emitting diodes (pc-LEDs) are demanded for wearable biosensing devices and the properties of these pc-LEDs are highly dependent on the performance of the NIR phosphor. An ultraviolet-visible and NIR-responded broadband NIR NaScGe2O6:Cr3+ phosphor is reported. Under 490 nm excitation, NaScGe2O6:Cr3+ shows broad emission band from 700 to 1250 nm, which covers the first and second NIR windows. An NIR pc-LED with radiant flux of 12.07 mW@350 mA is realized based on NaScGe2O6:Cr3+ and 450 nm blue LED chip. The ability of high-power NIR light of the NIR pc-LED to penetrate human tissues is observed successfully. Additionally, in NaScGe2O6:Cr3+, the luminescence performance of Cr3+ under 808 nm laser excitation is achieved for the first time.