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Rebuilding of the Burial Environment from the ChemicalBiography of Archeological Copper-Based Artifacts

机译:从化学品中重建埋葬环境考古铜基文物传记

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摘要

The long-term interaction between Cu-based alloys and environmental species gives rise to the formation of different and sometimes unusual compounds (i.e., the patina) with distinctive chemical and structural features as a function of the peculiar characteristics of the context. In this paper, we describe some representative case studies concerning degraded bronze Roman valuable or common use objects, and we show that an attentive study at a microscale level, as for forensic analysis, allows one to understand the chemical processes that underlie the formation of the surface alteration products. The achieved information describe fragments of chemical life and disclose the complex chemical changes suffered by the artifacts, allowing one to write their chemical biography. This challenging approach expands the panorama of available information and demonstrates that it is possible to reconstruct the different modes through which the bronze surfaces and interfaces have interacted with environmental species, organic matter, and microorganisms, opening up a new possibility to describe complex environmental chemicalstories, in certain cases interrelated.
机译:铜基合金与环境物种之间的长期相互作用会导致形成不同的,有时是不寻常的化合物(即古铜色),这些化合物具有独特的化学和结构特征,这取决于上下文的特殊特征。在本文中,我们描述了一些有关退化的古铜色罗马贵重物品或常用物品的代表性案例研究,并且我们表明,对于法医学分析,在微观水平上的细心研究可以使人们理解构成古铜色的化学过程。表面改变产品。所获得的信息描述了化学生命的片段,并揭示了人工制品遭受的复杂化学变化,从而使人们能够撰写其化学传记。这种具有挑战性的方法扩大了可用信息的范围,并表明可以重建青铜表面和界面与环境物种,有机物和微生物相互作用的不同模式,从而开辟了描述复杂环境化学物质的新可能性。故事,在某些情况下是相互关联的。

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