Single Crystal Growth and Crystal Structure Analysisof Novel Orange-Red Emission Pure Nitride CaAl2Si4N8:Eu2+ Phosphor

摘要

Single crystal of novel orange-red emission CaAl2Si4N8:Eu²⁺ phosphor was grown by our original vapor phase technique, and the precise crystal structure was investigated for the first time by single crystal X-ray diffraction analysis. The crystal structure of CaAl2Si4N8:Eu²⁺ single crystal was verified to be an α-Si3N4-type trigonal structure (space group P31c) with a = 0.79525(9) nm, c = 0.57712(8) nm, and z = 2. The Ca atoms were coordinated to seven nitrogen atoms and located in the three-dimensional framework formed by (Al, Si)N4 tetrahedra. The single-crystal CaAl2Si4N8:Eu²⁺ phosphors exhibited a broad reddish-yellow emission with a peak at 600 nm under near-UV and blue light excitation. When increasing the temperature up to 150 °C, the emission intensity of the CaAl2Si4N8:Eu²⁺ phosphor decreased to 88% of the initial value at 25 °C.