Silicon Industry Waste Polymethylhydrosiloxane-MediatedBenzotriazole Ring Cleavage: A Practical and Green Synthesis of DiverseBenzothiazoles

摘要

A green modification has been introduced to the synthesis of benzothiazoles by using polymethylhydrosiloxane (PMHS) for successive steps of benzotriazole ring cleavage and cyclization, an approach which was previously developed in our lab by the use of n-Bu3SnH. The use of the silicone industry byproduct PMHS makes this protocol a cost-effective and nontoxic one and thus may be considered for the industrial importance.