Noble Metal Nanoparticles Incorporated Siliceous TUD-1 Mesoporous Nano-Catalyst for Low-Temperature Oxidation of Carbon Monoxide

摘要

This report, for the first time, demonstrated the low-temperature oxidation of carbon monoxide (CO) using nano-catalysts consisting of noble metal nanoparticles incorporated in TUD-1 mesoporous silica nano-structures synthesized via a one-pot surfactant-free sol–gel synthesis methodology. Herein, we investigated a nano-catalyst, represented as M-TUD-1 (M = Rh, Pd, Pt and Au), which was prepared using a constant Si/M ratio of 100. The outcome of the analytical studies confirmed the formation of a nano-catalyst ranging from 5 to 10 nm wherein noble metal nanoparticles were distributed uniformly onto the mesopores of TUD-1. The catalytic performance of M-TUD-1 catalysts was examined in the environmentally impacted CO oxidation reaction to CO . The catalytic performance of Au-TUD-1 benchmarked other M-TUD-1 catalysts and a total conversion of CO was obtained at 303 K. The activity of the other nano-catalysts was obtained as Pt-TUD-1 > Pd-TUD-1 > Rh-TUD-1, with a total CO conversion at temperatures of 308, 328 and 348 K, respectively. The Au-TUD-1 exhibited a high stability and reusability as indicated by the observed high activity after ten continuous runs without any treatment. The outcomes of this research suggested that M-TUD-1 are promising nano-catalysts for the removal of the toxic CO gas and can also potentially be useful to protect the environment where a long-life time, cost-effectiveness and industrial scaling-up are the key approaches.