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The Effect of Waste Engine Oil and Waste Polyethylene on UV Aging Resistance of Asphalt

机译:废机油和废聚乙烯对沥青抗紫外线老化的影响

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摘要

Waste engine oil (WEO) and waste polyethylene (WPE) are two common wastes, which are easy to pollute the environment. As the primary material in road construction, natural asphalt is a non-renewable energy source and asphalt is vulnerable to ultraviolet (UV) radiation during the service life. It results in degradation of asphalt pavement performance. In this paper, 2 wt % to 8 wt % of WEO and WPE were used to modify asphalts and the UV aging simulation experiment was carried out. The physical parameters of asphalts before the UV aging experiment show that the asphalt containing 4 wt % WPE and 6 wt % WEO mixture (4 wt % WPE + 6 wt % WEO) has similar physical properties with that of the matrix asphalt. Besides, gel permeation chromatography (GPC) verifies that the molecular weight distribution of the asphalt containing 4 wt % WPE + 6 wt % WEO is close to that of the matrix asphalt. The storage stability test shows that 4 wt % WPE + 6 wt % WEO has good compatibility with the matrix asphalt. The functional groups and micro-morphology of asphalts before and after the UV aging experiment were investigated by Fourier transform infrared spectroscopy (FTIR) and atomic force microscopy (AFM). FTIR results display that 4 wt % WPE + 6 wt % WEO can effectively reduce the formation of carbonyl and sulfoxide functional groups. AFM shows that 4 wt % WPE + 6 wt % WEO can also retard the formation of a “bee-like” structure in asphalt after the UV aging experiment. Based on the above results, it can be concluded that WEO and WPE mixture can replace part of asphalt and improve the UV aging resistance of asphalt.
机译:废机油(WEO)和废聚乙烯(WPE)是两种常见废物,很容易污染环境。作为道路建设的主要材料,天然沥青是不可再生的能源,并且沥青在使用寿命期间易受紫外线(UV)辐射的影响。这导致沥青路面性能下降。本文使用2 wt%至8 wt%的WEO和WPE改性沥青,并进行了UV老化模拟实验。 UV老化实验之前的沥青物理参数显示,包含4 wt%WPE和6 wt%WEO混合物(4 wt%WPE + 6 wt%WEO)的沥青具有与基质沥青相似的物理性能。此外,凝胶渗透色谱法(GPC)验证包含4 wt%WPE + 6 wt%WEO的沥青的分子量分布与基体沥青的分子量分布接近。储存稳定性测试表明,4 wt%WPE + 6 wt%WEO与基质沥青具有良好的相容性。通过傅立叶变换红外光谱(FTIR)和原子力显微镜(AFM)研究了紫外线老化实验前后沥青的官能团和微观形貌。 FTIR结果表明,4 wt%WPE + 6 wt%WEO可以有效减少羰基和亚砜官能团的形成。原子力显微镜(AFM)显示,在紫外线老化试验之后,4 wt%的WPE + 6 wt%的WEO还可以阻止沥青中“蜂样”结构的形成。根据以上结果,可以得出结论,WEO和WPE混合物可以代替部分沥青并提高沥青的抗紫外线老化性能。

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