Prickly pear cactus cladodes powder of Opuntia ficus indica as a cost effective biosorbent for dyes removal from aqueous solutions

摘要

The textiles manufacturing is one of the core industries that release a huge amount of dyes during the dyeing process. As a result, the growing demand of an efficient and low-cost treatment has given rise to alternative adsorbents. In the present study, prickly pear cactus cladodes powder (PPCP) of Opuntia ficus indica was investigated as an ecofriendly and low-cost biosorbent of Acid orange 51 (AO51) and Reactive Red 75 (RR75) dyes commonly used in dyeing. The FTIR spectroscopic characterization of PPCP showed the heterogeneity in surface structure and functional groups which confers to the biosorbent its capability to interact with acidic (AO51) and reactive (RR75) dyes molecules. Effects of pH, temperature, initial dye concentration and adsorbent dose on adsorption yield were investigated. The dyes uptake process was closely fitted to the pseudo-second order kinetic for both dyes. Experimental data were analyzed by applying the Langmuir, Freundlich, Dubinin–Raduskevich, Temkin, Redlich–Peterson, and BET isotherms equations. The models of BET and Langmuir were considered as the best isotherms models fitting experimental data, respectively, of RR75 and AO51. The maximum Langmuir monolayer biosorption capacities were of 198.9 and 45 mg g⁻¹, respectively for RR75 and AO51.