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Solution-processable graphene nanomeshes with controlled pore structures

机译:具有可控孔结构的溶液可加工石墨烯纳米网

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摘要

Graphene nanomeshes (GNMs) which can be cheaply produced on a large scale and processed through wet approaches are important materials for various applications, including catalysis, composites, sensors and energy related systems. Here, we report a method for large scale preparation of GNMs by refluxing reduced graphene oxide sheets in concentrated nitric acid solution (e.g., 8 moles per liter). The diameters of nanopores in GNM sheets can be readily modulated from several to hundreds nanometers by varying the time of acid treatment. The porous structure increased the specific surface areas of GNMs and the transmittances of GNM-based thin films. Furthermore, GNMs have large number of carboxyl groups at the edges of their nanopores, leading to good dispersibility in aqueous media and strong peroxidase-like catalytic activity.
机译:可以大规模廉价地生产并通过湿法加工的石墨烯纳米网格(GNM)是用于各种应用(包括催化,复合材料,传感器和能源相关系统)的重要材料。在这里,我们报告了一种通过在浓硝酸溶液中回流还原的氧化石墨烯片(例如每升8摩尔)大规模制备GNM的方法。通过改变酸处理时间,可以轻松地将GNM薄片中的纳米孔直径从几纳米调节到几百纳米。多孔结构增加了GNM的比表面积和基于GNM的薄膜的透射率。此外,GNM在其纳米孔的边缘具有大量的羧基,从而导致其在水性介质中的良好分散性和强的过氧化物酶样催化活性。

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