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Dissociation and Ionization of Quasi-Periodically Vibrating H2+ in Intense Few-Cycle Mid-Infrared Laser Fields

机译:强周期短周期中红外激光场中准周期振动的H2 +的解离和电离

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摘要

Using quantum mechanics calculations, we theoretically study the dissociation and ionization dynamics of the hydrogen-molecule ion in strong laser fields. Having prepared the nuclear wave packet of H2+ in a specific vibrational state, a pump laser is used to produce a vibrational excitation, leading to quasi-periodical vibration without ionization. Then, a time-delayed few-cycle laser is applied to trigger the dissociation or ionization of H2+. Both the time delay and the intensity of the probe laser alter the competition between dissociation and ionization. We also explore the dependence of kinetic-energy release spectra of fragments on the time delay, showing that the channels of above-threshold dissociation and below-threshold dissociation are opened and closed periodically. Also, dissociation from different channels is influenced by nuclear motion. The dissociation mechanism has been described in detail using the Floquet picture. This work provides a useful method for steering the electronic and nuclear dynamics of diatomic molecules in intense laser fields.
机译:使用量子力学计算,我们从理论上研究了强激光场中氢分子离子的解离和电离动力学。在特定的振动状态下制备H2 + 的核波包后,将泵浦激光器用于产生振动激励,从而导致准周期振动而不会电离。然后,使用延时的几个周期激光触发H2 + 的解离或电离。时间延迟和探测激光的强度都会改变解离和电离之间的竞争。我们还探索了片段的动能释放谱对时间延迟的依赖性,表明阈上解离和阈下解离的通道是周期性打开和关闭的。而且,来自不同通道的解离受核运动影响。已经使用Floquet图片详细描述了离解机制。这项工作为控制强激光场中双原子分子的电子和核动力学提供了一种有用的方法。

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