trans-Tris(4-bromo­phen­yl)dichlorido­antimony(V)

摘要

The Sb^V atom in the title compound, [SbCl2(C6H4Br)3], has an almost regular trigonal–bipyramidal geometry with the equatorial plane made up of three C atoms of the bromo­phenyl groups and the axial positions occupied by two Cl⁻ ions in a trans configuration. In the crystal, C—H⋯Br hydrogen bonds link the mol­ecules into zigzag chains along the b-axis direction. Pairs of C—H⋯Cl hydrogen bonds further link mol­ecules into cyclic dimers with R 2 ²(10) ring motifs, generating a three-dimensional network.