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A review of carbon-based and non-carbon-based catalyst supports for the selective catalytic reduction of nitric oxide

机译:关于选择性催化还原一氧化氮的碳基和非碳基催化剂载体的综述

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摘要

Various types of carbon-based and non-carbon-based catalyst supports for nitric oxide (NO) removal through selective catalytic reduction (SCR) with ammonia are examined in this review. A number of carbon-based materials, such as carbon nanotubes (CNTs), activated carbon (AC), and graphene (GR) and non-carbon-based materials, such as Zeolite Socony Mobil–5 (ZSM-5), TiO2, and Al2O3 supported materials, were identified as the most up-to-date and recently used catalysts for the removal of NO gas. The main focus of this review is the study of catalyst preparation methods, as this is highly correlated to the behaviour of NO removal. The general mechanisms involved in the system, the Langmuir–Hinshelwood or Eley–Riedeal mechanism, are also discussed. Characterisation analysis affecting the surface and chemical structure of the catalyst is also detailed in this work. Finally, a few major conclusions are drawn and future directions for work on the advancement of the SCR-NH3 catalyst are suggested.
机译:在这篇综述中,研究了各种类型的碳基和非碳基催化剂载体,这些载体通过氨选择性催化还原(SCR)去除一氧化氮(NO)。许多碳基材料,例如碳纳米管(CNT),活性炭(AC)和石墨烯(GR),以及非碳基材料,例如Zeolite Socony Mobil-5(ZSM-5),TiO2,以及以Al2O3为载体的材料被确定为是最新的且最近用于去除NO气体的催化剂。这篇综述的主要重点是催化剂制备方法的研究,因为这与脱除NO的行为高度相关。还讨论了系统中涉及的一般机制,即Langmuir–Hinshelwood或Eley–Riedeal机制。在这项工作中还详细描述了影响催化剂表面和化学结构的表征分析。最后,得出了一些主要结论,并提出了发展SCR-NH3催化剂的未来工作方向。

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