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Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

机译：沮丧的路易斯对基引发剂控制氰基丙烯酸酯的活性阴离子聚合

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A hydrogenated frustrated Lewis pair ([TMPH⁺][HB(C6F5)3^–]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials.

机译：氢化沮丧的路易斯对（[TMPH ^{+ ] [HB（C6F5）3 ^{– ]）促进了氰基丙烯酸酯的受控活性离子聚合。除了在这些材料的悠久历史中首次具有具有受控嵌段序列的CA嵌段共聚物之外，还通过单体的顺序添加实现了各种均聚物CA的受控生长。}}

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期刊名称 Chemical Science
作者
Rubén Sáez; Ciaran McArdle; Fouad Salhi; Jordi Marquet; Rosa M. Sebastián;
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年(卷),期 2019(10),11
年度 2019
页码 3295–3299
总页数 5
原文格式 PDF
正文语种
中图分类生化遗传学;生化药理学;
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专利

1. Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators [J] . Rubén Sáez, Ciaran McArdle, Fouad Salhi, Chemical science . 2019,第11期

机译：沮丧的路易斯对引发剂控制氰基丙烯酸酯的活性阴离子聚合
2. Lewis pair polymerization by classical and frustrated Lewis pairs: Acid, base and monomer scope and polymerization mechanism [J] . Zhang Y., Miyake G.M., John M.G., Dalton transactions: An international journal of inorganic chemistry . 2012,第30期

机译：路易斯和经典路易斯对的路易斯对聚合：酸，碱和单体的范围和聚合机理
3. Living Polymerization of Conjugated Polar Alkenes Catalyzed by N-Heterocyclic Olefin-Based Frustrated Lewis Pairs [J] . Qianyi Wang, Wuchao Zhao, Sutao Zhang, ACS catalysis . 2018,第4期

机译：由 N-I>催化的共轭极性烯烃的生物聚合 - 基于元环烯烃的令人沮丧的刘易斯对
4. LITHIATED THIOACETALS AS INITIATORS FOR LIVING ANIONIC POLYMERIZATION OF DIENE ELASTOMERS. POLYMERIZATION AND COMPOUNDING [C] . Terrence E. Hogan, Yuan-Yong Yan, William L. Hergenrother, Fall 170th Technical Meeting of the Rubber Division, American Chemical Society(ACS) . 2006

机译：锂化硫缩甲醛作为引发二烯弹性体阴离子聚合的引发剂。聚合和复合
5. Boron-Based Lewis Acids: Towards Intramolecular Frustrated Lewis Pairs and Enantioselective Catalysis [D] . Lam, Jolie Zi Ning. 2020

机译：基于硼的路易斯酸：朝向分子内沮丧的刘易斯对和对映选择性的催化
6. Controlled and Efficient Polymerization of Conjugated Polar Alkenes by Lewis Pairs Based on Sterically Hindered Aryloxide-Substituted Alkylaluminum [O] . Xiaojun Wang, Yixin Zhang, Miao Hong 2018

机译：刘易斯对基于立体受阻的芳醇取代烷基铝的共轭极性烯烃的控制和高效聚合
7. Inside Cover: Alane-Based Classical and Frustrated Lewis Pairs in Polymer Synthesis: Rapid Polymerization of MMA and Naturally Renewable Methylene Butyrolactones into High-Molecular-Weight Polymers (Angew. Chem. Int. Ed. 52/2010) [O] . Yuetao Zhang, Garret M. Miyake, Eugene Y.-X. Chen 2010

机译：内盖：基于alane的古典和沮丧的路易斯对在聚合物合成中：MMA和天然可再生亚甲丁内酯的快速聚合到高分子量聚合物中（Angew.Chem.Int.de。52/2010）
8. Polymethyl Alpha Cyanoacrylates:Ⅰ. Molecular Weight Determination by Light Scattering. Ⅱ. Effect of Various Anionic Initiators on Terminal Structure. [R] . R. K. Kulkarni, Harold J. Porter 1965

机译：聚氰基丙烯酸甲酯：Ⅰ。光散射法测定分子量。 Ⅱ。不同阴离子引发剂对末端结构的影响。

Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

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