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Minimum Burning Pressures of Water-based Emulsion Explosives

机译:水性乳化炸药的最低燃烧压力

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摘要

This manuscript describes a protocol to measure the minimum pressure required for sustained burning of water-based emulsion explosives. Pumping water-based emulsion explosives for blasting applications can be very hazardous, as demonstrated by a number of pump accidents around the globe in the last decades, including some that resulted in fatalities. In Canada, the recognition of this hazard has led to the development of pumping guidelines that were endorsed by both the explosives industry and the Explosive Regulatory Division of the Canadian government. In these guidelines, it was noted that the minimum burning pressures (MBP) measured in a laboratory would provide a good guide to characterize the behaviour of these products in pumping systems. The same guidelines also call for the design of pump systems that prevent, whenever possible, pressures from exceeding the MBP of the product being pumped. At the time of publication of these guidelines, a methodology existed for measuring such MBP values but it had never been validated to measure the MBP of ammonium nitrate water-based emulsions (AWEs). AWEs are now used much more widely than any other water-based explosives and precursors in on-site bulk loading operations.The Canadian Explosives Research Laboratory (CanmetCERL) has been conducting research over the last ten years to develop a validated testing protocol to measure and interpret representative MBP values for AWEs. The test, as it is performed today, will be described and the critical components will be justified by reference to recent published data. Results of MBP measurements, for a range of AWE products, will be presented. Inclusion of the MBP test in the test standards for the authorization of high explosives in Canada will also be discussed.
机译:该手稿描述了一种用于测量持续燃烧水基乳化炸药所需的最小压力的方案。泵送水基乳化炸药用于爆破应用可能非常危险,最近几十年来在全球范围内发生了许多泵事故,包括造成死亡的事故。在加拿大,对这种危害的认识导致了爆炸准则的制定,该准则得到爆炸物行业和加拿大政府爆炸物管理部门的认可。在这些准则中,应指出,在实验室中测量的最低燃烧压力(MBP)将为表征这些产品在泵系统中的行为提供良好的指导。相同的准则还要求设计泵系统,以尽可能防止压力超过被泵送产品的MBP。在发布这些指南时,已经存在一种用于测量此类MBP值的方法,但从未经过验证可用于测量硝酸铵水基乳液(AWE)的MBP。在现场散装装载作业中,AWE的使用比任何其他水性炸药和前体都要广泛。加拿大炸药研究实验室(CanmetCERL)在过去十年中一直在进行研究,以开发一种经过验证的测试方案来测量和测量解释AWE的代表性MBP值。将描述今天进行的测试,并通过参考最近发布的数据来证明关键组件的合理性。将介绍一系列AWE产品的MBP测量结果。还将讨论将MBP测试纳入加拿大高爆炸物授权测试标准中。

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