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In Situ Representation of Soil/Sediment Conductivity Using Electrochemical Impedance Spectroscopy

机译:用电化学阻抗谱法原位表示土壤/沉积物的电导率

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摘要

The electrical conductivity (EC) of soil is generally measured after soil extraction, so this method cannot represent the in situ EC of soil (e.g., EC of soils with different moisture contents) and therefore lacks comparability in some cases. Using a resistance measurement apparatus converted from a configuration of soil microbial fuel cell, the in situ soil EC was evaluated according to the Ohmic resistance (Rs) measured using electrochemical impedance spectroscopy. The EC of soils with moisture content from 9.1% to 37.5% was calculated according to Rs. A significant positive correlation (R2 = 0.896, p < 0.01) between the soil EC and the moisture content was observed, which demonstrated the feasibility of the approach. This new method can not only represent the actual soil EC, but also does not need any pretreatment. Thus it may be used widely in the measurement of the EC for soils and sediments.
机译:土壤的电导率(EC)通常是在土壤提取后测量的,因此该方法无法表示土壤的原位EC(例如,水分含量不同的土壤的EC),因此在某些情况下缺乏可比性。使用从土壤微生物燃料电池的构造转换而来的电阻测量装置,根据使用电化学阻抗谱法测量的欧姆电阻(Rs)来评估原位土壤EC。根据Rs计算出水分含量为9.1%至37.5%的土壤的EC。土壤EC与含水量之间存在显着的正相关关系(R 2 = 0.896,p <0.01),证明了该方法的可行性。这种新方法不仅可以代表实际的土壤EC,而且不需要任何预处理。因此,它可以广泛用于土壤和沉积物EC的测量。

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