Zinc recovery from metallurgical slag and dust by coordination leaching in NH3–CH3COONH4–H2O system

摘要

Metallurgical slag and dust (MSD) from lead and zinc smelting, steel dust and galvanized steel scrap are important secondary sources of zinc and other valuable metals. This paper describes the production feasibility and rationality of a cleaner zinc recovery process using MSD and a hydrometallurgical method. It was found that the addition of CH3COONH4 to a NH3–H2O system promotes zinc extraction, and 83.76% of zinc could be dissolved and recovered from the MSD under the following conditions: total ammonia concentration of 5 mol l⁻¹, stirring speed of 300 r.p.m., ammonia/ammonium ratio of 1 : 1, solid/liquid ratio of 1 : 5, leaching temperature of 25°C and a leaching time of 60 min. A leaching kinetic study indicates that the leaching process is controlled by the diffusion and interface transfer and that the reaction apparent activation energy is 22.66 kJ mol⁻¹. Fourier transform infrared spectroscopy and electrospray ionization mass spectrometry analysis showed that zinc can combine with the carboxylate anion to form Zn complexes such as [Zn2(Ac)3(NH3)2]⁺. Zn2SiO4, ZnS and ZnFe2O4 in NH3–CH3COONH4–H2O system did not disappear according to X-ray diffraction analysis for leaching residue.