Tris(μ2-methano­lato)-μ3-oxido-tris­{(E)-4-chloro-2-({2-(pyridin-2-yl)eth­ylimino}­meth­yl)pheno­latomanganese(III)} perchlorate–di­chloro­methane–diethyl ether (1/1.1/0.9)

摘要

In the title compound, [Mn3(C14H12ClN2O)3(CH3O)3O]ClO4·1.1CH2Cl2·0.9C4H10O, the cation consists of a central Mn3O core with μ2-methano­late bridging between adjacent Mn^III atoms, thus giving each Mn^III atom a mer-O3 coordination environment. Six-coordination for each Mn^III atom is provided by the deprotonated Schiff base ligand (E)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolate. There are extensive C—H⋯O and C—H⋯Cl inter­actions, which link the cations, anions, and solvent mol­ecules into a three-dimensional array.