A Facile Approach for Preparing Ag Functionalized Nonwoven Polypropylene Membrane to Improve Its Electrical Conductivity and Electromagnetic Shielding Performance

摘要

The commonly used preparation methods of polypropylene functionalization require special equipment to be put into use or take a long time, which limits its application. Therefore, a simple and economical method for preparing silver functionalized nonwoven polypropylene membrane was studied herein. Triethanolamine was first coated on the surface of the polypropylene, and then Ag was deposited on the surface of polypropylene using a continuous reduction reaction of triethanolamine and silver ions. Surface morphology, crystal structure, and surface chemistry during the preparation of Ag functionalized nonwoven polypropylene were investigated. The electrical conductivity, electromagnetic shielding properties, and washing durability of the treated nonwoven polypropylene were also studied. It was found that Ag was uniformly deposited on the surface of the nonwoven polypropylene, and the coating reaction did not change the chemical structure of the polypropylene. The crystallinity and thermal stability of polypropylene were improved after silver coated polypropylene. The washing experiment results showed that the weight gain rate of the treated nonwoven relative to the untreated sample after the 90 min washing ranged from 6.72% to 9.64%. The resistance test results showed that the maximum surface resistivity of Ag coated nonwoven polypropylene was about 1.95 × 10⁵ Ω, which was 64,615 times lower than the original. In addition, the results showed that the maximum electromagnetic shielding effectiveness of the Ag coated nonwoven polypropylene was about 71.6 dB, showing a very good electromagnetic shielding effect.