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The Application of Electrical Parameters to Reflect the Hydration Process of Cement Paste with Rice Husk Ash

机译:电参数在反映稻壳灰水泥浆水化过程中的应用

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摘要

This paper aims to study the electrical parameters (electrical resistivity and alternating current (AC) impedance spectroscopy) of cement paste with rice husk ash (RHA). The water to cement (Mass ratio of water to cement (w/c)) ratios of the paste in this study varied from 0.4 to 0.5. The mass ratio of rice husk ash in each w/c ratio of specimens ranged from 0% to 15% by t mass of cement. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to determine the microstructures of specimens. Moreover, the slump flow and plastic viscosity of fresh paste were determined. The results indicated that with the increasing dosage of RHA, the fluidity decreased, while the plastic viscosity increased. Meanwhile, a high w/c ratio led to a low plastic viscosity and high slump flow. The electrical resistivity of RHA cement paste gradually ascended with the increasing curing period. The conduction of specimens intricately changed by mixing RHA, a reasonable equivalent circuit was selected to describe the conduction mechanism by AC impedance spectroscopy. Additionally, the results of XRD and SEM showed that RHA could effectively promote the hydration process as well as decrease the size and number of cracks in hardened cement paste.
机译:本文旨在研究稻壳灰(RHA)水泥浆的电参数(电阻率和交流(AC)阻抗谱)。在这项研究中,糊的水与水泥(水与水泥的质量比(w / c))之比在0.4到0.5之间变化。以水泥的t质量计,每个样品的w / c比中稻壳灰的质量比为0%至15%。扫描电子显微镜(SEM)和X射线衍射(XRD)用于确定样品的显微结构。此外,确定了新鲜糊的坍落度和塑性粘度。结果表明,随着RHA用量的增加,流动性降低,塑性粘度增加。同时,高的w / c比导致低的塑料粘度和高的坍落度流动。随着固化时间的延长,RHA水泥浆的电阻率逐渐升高。通过混合RHA可以使样品的导电性发生复杂的变化,选择了一个合理的等效电路来描述交流阻抗谱的导电机理。此外,XRD和SEM的结果表明,RHA可以有效地促进水化过程,并减少硬化水泥浆中裂缝的大小和数量。

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