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Dynamical inversion of the energy landscape promotes non-equilibrium self-assembly of binary mixtures

机译:能量格局的动态反转促进了二元混合物的非平衡自组装

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摘要

When driven out of equilibrium, many diverse systems can form complex spatial and dynamical patterns, even in the absence of attractive interactions. Using kinetic Monte Carlo simulations, we investigate the phase behavior of a binary system of particles of dissimilar size confined between semiflexible planar surfaces, in which the nanoconfinement introduces a non-local coupling between particles, which we model as an activation energy barrier to diffusion that decreases with the local fraction of the larger particle. The system autonomously reaches a cyclical non-equilibrium state characterized by the formation and dissolution of metastable micelle-like clusters with the small particles in the core and the large ones in the surrounding corona. The power spectrum of the fluctuations in the aggregation number exhibits 1/f noise reminiscent of self-organized critical systems. We suggest that the dynamical metastability of the micellar structures arises from an inversion of the energy landscape, in which the relaxation dynamics of one of the species induces a metastable phase for the other species.
机译:当失去平衡时,即使没有有吸引力的相互作用,许多不同的系统也可以形成复杂的空间和动力模式。使用动力学蒙特卡洛模拟,我们研究了限制在半柔性平面之间的大小不同的二元颗粒的二元系统的相行为,其中纳米约束在颗粒之间引入了非局部耦合,我们将其建模为扩散的激活能垒随较大颗粒的局部分数降低。该系统自动达到周期性的非平衡状态,其特征是亚稳态的胶束状团簇的形成和溶解,其中的小颗粒位于核心,大颗粒位于周围的电晕。聚集数波动的功率谱显示出1 / f噪声,使人想起自组织的关键系统。我们建议,胶束结构的动力学亚稳态源于能量格局的反转,其中一种物种的弛豫动力学诱发了另一种物种的亚稳态。

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