关于理想气体反应K(○)c的特殊性和K(○)c应用于过渡态理论中错误的纠正

摘要

主要论述理想气体分别在等温等压下反应和在等温等容下反应的标准平衡常数K(○)分别选择不同浓标P(○),C(○)时四种不同标准平衡常数对温度变化响应的差异性,由此看出K(○)c的特殊性.进行了严密的理论推导,并深入分析了造成这种差异的原因.并对四种不同标准平衡常数在过渡态理论的应用中得出的四种活化能和四种速率常数长期以来的错误进行了纠正.%In this article, it is strictly deduced that four different kinds of standard equilibrium con-stants K -of ideal gas reactions show different response to change of temperature for the difference between concentration scale P(○) and C(○) with isobaric or isochoric reaction condition. The theoretical reason of the difference is analyzed thoroughly. And the error of application of four different kinds of standard equilibrium constants that has existed for a long time is corrected with four different kinds of rate constants and activation energy in transition state theory.