A sol-gel method was employed to prepare M(= Ni, Ce, Cu)xOy/ZrO2-γ-Al2O3 and M( =NJ, Ce, Cu)xOy/YSZ-γ-Al2O3 catalysts. The effects of M on CH4 Catalytic combustion properties of support were investigated contrastively and characterized by XRD, BET and TPR techniques. The results showed Catalytic combustion properties of support were improved by Y2O3. CuO/YSZ-γ-Al2O3 catalysts was found to has the highest catalytic activity, but it might be sintered partly by second run of the catalytic evaluation, because some active components CuO and vector generated lower activity CuAl2O4. NiO/YSZ-γ-Al2O3 had the highest thermal stability and the performances of CeO2/YSZ-γ-Al2O3 between CuO/YSZ-γ-Al2O3 and NiO/YSZ-γ-Al2O3. In the same time, BET, XRD and H2-TPR results indicated further that MxOy/YSZ-γ-Al2O3 catalysts were possessed bigger surface area and better ability to resist sintering.%以溶胶凝胶法制备(NiO、CuO、CeO2)/ZrO2-γ-Al2O3和(NiO、CuO、CeO2)/YSZ-γ-Al2O3催化剂.分别考察了负载3种不同单一活性组分对载体的催化甲烷燃烧性能的影响,并以BET、XRD、H2-TPR等测试法,对催化剂进行了表征.实验结果表明,经Y2O3改性载体的催化剂性能较佳.其中CuO/YSZ-γ-Al2O3催化剂活性较好,但该催化剂二次评价后因有部分活性组分与载体生成低活性的CuAl2O4且部分烧结;NiO/YSZ-γ-Al2O3稳定性较好,且改性效果明显;CeO2/YSZ-γ-Al2O3催化剂活性居中,稳定性较好.测试结果表明,NiO、CeO2为活性组分的催化剂比表面较大和抗烧结能力较强.
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