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Site Preferences of Pr and Co in(Nd,Pr)_2(Fe,Co)_(14)B Compounds

         

摘要

The Curie temperature of(Nd1-xPrx)2Fe14CoyB compounds(x=0,0.2,…,1.0 and y=O,2,4,6,14)hasbeen determined with AC initial susceptibility measurement.It was found that the variations of Curie tempera-ture with x is not linear for y=0 and 14,whereas it is linear for other values of y.The lattice constants of(Nd1-xPrx)2Fet14B were determined by using X-ray diffraction.The lattice expansion was mostly along the caxis,whereas that along the a-axis remained practically zero for the whole series.It is suggested that Pr atomsmay show site preference in R2M14B compounds(M=Fe or Co).Due to the substitution of Co for Fe.thetendency of site preference of Pr becomes less pronounced,which may be attributed to the decrease of differ-ence of crystal electric field(CEF)acting on the two rare earth sites with the introduction of Co or Fe.In con-trast to that of the Pr atoms,the site preference of Co iu(Nd(1-x)Prx)2Fe(14-y)CoyB compounds does not depend onthe composition of the rare earth sublattice(R=N d or Pr).

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